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Statistical mechanics with topological constraints: I

Open access
Edwards, S F·1967·Proceedings of the Physical Society

Abstract

The entropy of very long flexible molecules in the presence of topological constraints is studied, and a formula deduced which needs the probability that a random walk will have a particular topological specification. Examples are solved, including a plane random walk sweeping out a given angle around a point in the plane which is generalized to three dimensions including the passage of a random walk past many lines in space, and the probability that a random walk will penetrate through or become multiply entangled with a closed ring.

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Metadata

Authors
Edwards, S. F.
Venue
Proceedings of the Physical Society
Published
1967-07
Volume
91
Issue
3
Pages
513-519
ISSN
0370-1328 (ISSN-L)
OpenAlex
W2015031142
Cited by
454
References
0
FWCI
2.01
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Statistical mechanics with topological constraints: I. https://app.cochat.ai/papers/10.1088/0370-1328/91/3/301
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Edwards, S. F. (1967). Statistical mechanics with topological constraints: I. Proceedings of the Physical Society. https://doi.org/10.1088/0370-1328/91/3/301

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.