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Universal features of the equation of state of solids
Open accessAbstract
A study of the energetics of solids leads to the conclusion that the equation of state for all classes of solids in compression can be expressed in terms of a universal function. The form of this universal function is determined by sealing experimental compression data for measured isotherms of a wide variety of solids. The equation of state is thus known (in the absence of phase transitions), if zero-pressure volume and isothermal compression and its pressure derivative are known. The discovery described by the authors has two immediate consequences: first, despite the well known differences in the microscopic energetics of the various classes of solids, there is a single equation of state for all classes in compression; and second, a new method is provided for analysing measured isotherms and extrapolating high-pressure data from low-pressure (e.g. acoustic) data.
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Cited by
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Xie, Y., Dall’Agnese, Y., Naguib, M., Gogotsi, Y., Barsoum, M. W., Zhuang, H. L., & Kent, P. R. C. (2014) · ACS Nano · doi:10.1021/nn503921j · Cited by 1,046
Gibbs2: A new version of the quasi-harmonic model code. I. Robust treatment of the static data
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Perryman, M. (2018) · Cambridge University Press eBooks · doi:10.1017/9781108304160 · Cited by 340
Metadata
- Authors
- Vinet, P., Rose, J. H., Ferrante, J., & Smith, J. R.
- Venue
- Journal of Physics: Condensed Matter
- Publisher
- IOP Publishing
- Published
- 1989-03-20
- Volume
- 1
- Issue
- 11
- Pages
- 1941-1963
- ISSN
- 0953-8984 (ISSN-L)
- 1361-648X
- OpenAlex
- W2043483114
- Cited by
- 1,055
- References
- 0
- FWCI
- 5.60
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Vinet, P., Rose, J. H., Ferrante, J., & Smith, J. R. (1989). Universal features of the equation of state of solids. Journal of Physics: Condensed Matter. https://doi.org/10.1088/0953-8984/1/11/002
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