Cited by 343Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric materials and actuators

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Contribution of the irreversible displacement of domain walls to the piezoelectric effect in barium titanate and lead zirconate titanate ceramics

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Damjanovic, Dragan, Demartin, Marlyse·1997·Journal of Physics Condensed Matter

DOI 10.1088/0953-8984/9/23/018

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Abstract

The contribution from the irreversible displacement of non- domain walls to the direct longitudinal piezoelectric coefficient of and ceramics was determined quantitatively by using the Rayleigh law. Effects of the crystal structure and microstructure of the ceramics as well as the external d.c. pressure on the domain wall contribution to were examined. In barium titanate, this domain wall contribution is large (up to 35% of the total , under the experimental conditions used) and dependent on the external d.c. pressure in coarse grained ceramics, and much smaller and independent of the external d.c. pressure in fine-grained samples. The presence of internal stresses in fine-grained ceramics could account for the observed behaviour. The analysis shows that the domain-wall contribution to the in lead zirconate titanate ceramics is large in compositions close to the morphotropic phase boundary that contain a mixture of tetragonal and rhombohedral phases, and in rhombohedral compositions (up to 40% of the total ). The domain-wall contribution to the piezoelectric response from the irreversible displacement of domain walls is significantly smaller in tetragonal samples where it decreases with increasing spontaneous strain.

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Authors: Damjanovic, D., & Demartin, M.
Affiliations: École Polytechnique Fédérale de Lausanne (CH)
Venue: Journal of Physics Condensed Matter
Publisher: IOP Publishing
Published: 1997-06-09
Volume: 9
Issue: 23
Pages: 4943-4953
ISSN: 0953-8984 (ISSN-L)
1361-648X
DOI: 10.1088/0953-8984/9/23/018
OpenAlex: W2001930249
Cited by: 343
References: 15
Citations by year: 2026: 3 · 2025: 19 · 2024: 19 · 2023: 12 · 2022: 22 · 2021: 15 · 2020: 20 · 2019: 9 · 2018: 11 · 2017: 19 · 2016: 15 · 2015: 13 · 2014: 20 · 2013: 17 · 2012: 17
FWCI: 3.92
Type: journal article
Language: en
Open access: bronze
doi.org
Locations: Journal of Physics Condensed Matter (publishedVersion)
Infoscience (Ecole Polytechnique Fédérale de Lausanne) (submittedVersion)
Infoscience (Ecole Polytechnique Fédérale de Lausanne) (submittedVersion, cc-by-nc-nd)
Funders: National Science Foundation
Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung
Topics: Physical Sciences › Materials Science › Materials Chemistry › Ferroelectric and Piezoelectric Materials
Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Multiferroics and related materials
Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Dielectric materials and actuators
Keywords: domain walls, piezoelectric properties, barium titanate, lead zirconate titanate, Rayleigh law, fine-grained ceramics, internal stress, morphotropic phase boundary, spontaneous strain, ferroelectric ceramics

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Contribution of the irreversible displacement of domain walls to the piezoelectric effect in barium titanate and lead zirconate titanate ceramics

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