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Small Ti clusters for catalysis of hydrogen exchange in NaAlH4
Open accessAbstract
Colloidal Ti has been synthesized following a method described in the literature. Extended x-ray absorption fine structure measurements indicate the presence of small colloidal entities, consisting of only a few core Ti atoms which are coordinated by O atoms from tetrahydrofuran (THF). The results can be explained by the proposed structure of Ti 13 · 6THF, in which the Ti cluster has the shape of a distorted icosahedron. The Ti colloid was used to prepare a functional nanocomposite by ball-milling the clusters with NaAlH 4 . The nanocomposite showed superior hydrogen exchange kinetics when compared to the state of the art in the literature.
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Cited by
Metal hydride materials for solid hydrogen storage: A review
SAKINTUNA, B., LAMARIDARKRIM, F., & HIRSCHER, M. (2007) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2006.11.022 · Cited by 3,715
Complex Hydrides for Hydrogen Storage
Orimo, S.-I., Nakamori, Y., Eliseo, J. R., Züttel, A., & Jensen, C. M. (2007) · Chemical Reviews · doi:10.1021/cr0501846 · Cited by 2,318
Hydrogen Storage Materials for Mobile and Stationary Applications: Current State of the Art
Lai, Q., Paskevicius, M., Sheppard, D. A., Buckley, C. E., Thornton, A. W., Hill, M. R., Gu, Q., Mao, J., Huang, Z., Liu, H. K., et al. (2015) · ChemSusChem · doi:10.1002/cssc.201500231 · Cited by 414
Metadata
- Authors
- Fichtner, M., Fuhr, O., Kircher, O., & Rothe, J. R.
- Venue
- Nanotechnology
- Publisher
- IOP Publishing
- Published
- 2003-05-13
- Volume
- 14
- Issue
- 7
- Pages
- 778-785
- ISSN
- 0957-4484 (ISSN-L)
- 1361-6528
- OpenAlex
- W2171200659
- Cited by
- 183
- References
- 0
- FWCI
- 13.78
- Type
- journal article
- Language
- en
- Open access
- bronze
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