The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
The stability of halloysite nanotubes in acidic and alkaline aqueous suspensions
Abstract
The long term stability of natural halloysite nanotubes was studied at room temperature (22 ± 2 °C) in pure water, acidic and basic aqueous suspensions. The structural and morphological transformations of nanotubes were studied by TEM, SEM, nitrogen adsorption, XRD Raman and FTIR spectroscopy accompanied by monitoring the concentration of dissolved Si(IV) and Al(III) in solution. It has been revealed that, in 1 mol dm(-3) H(2)SO(4) solution, the dissolution of halloysite is initiated on the inner surface of nanotubes, leading to the formation of amorphous spheroidal nanoparticles of SiO(2) whereas, in 1 mol dm(-3) NaOH solution, dissolution of the inner surface of nanotubes is accompanied by the formation of Al(OH)(3) nanosheets.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the citing paper
“A peak at 20.3° is observed which is one of the characteristic peaks of HNT that related to (020/110) plane (Liao et al., 2016). The location of this peak has not changed due to the scaffolding production process, which indicates that the HNT layers do not change and that the HNT and gelatin do not intercalate (White et al., 2012).”
From Osteogenesis Improvement of Gelatin-Based Nanocomposite Scaffold by Loading Zoledronic Acid (2022) · cites this paper as White et al., 2012
Citations
Cites
Adsorption Surface Area and Porosity
Gregg, S. J., Sing, K. S. W., & Salzberg, H. W. (1967) · Journal of The Electrochemical Society · doi:10.1149/1.2426447 · Cited by 9,530
Adsorption surface area and porosity
Steele, W. A. (1983) · Journal of Colloid and Interface Science · doi:10.1016/0021-9797(83)90305-3 · Cited by 7,946
Crystal Structures of Clay Minerals and their X-Ray Identification
(1980) · Mineralogical Society of Great Britain and Ireland eBooks · doi:10.1180/mono-5 · Cited by 3,504
Physical Adsorption on Non-Uniform Surfaces
Halsey, G. D. (1948) · The Journal of Chemical Physics · doi:10.1063/1.1746689 · Cited by 1,480
Halloysite clay minerals — a review
Joussein, E., Petit, S., Churchman, G. J., Theng, B. K. G., Righi, D., & Delvaux, B. (2005) · Clay Minerals · doi:10.1180/0009855054040180 · Cited by 1,440
Functionalization of Halloysite Clay Nanotubes by Grafting with γ-Aminopropyltriethoxysilane
Yuan, P., Southon, P. D., Liu, Z., et al. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp805657t · Cited by 968
Introduction to mineral sciences
Putnis, A. (1992) · Cambridge University Press eBooks · doi:10.1017/cbo9781139170383 · Cited by 817
The effect of hydrothermal conditions on the mesoporous structure of TiO2 nanotubes
Bavykin, D. V., Parmon, V. N., Lapkin, A. A., & Walsh, F. C. (2004) · Journal of Materials Chemistry · doi:10.1039/b406378c · Cited by 734
Self-citationNewly emerging applications of halloysite nanotubes: a review
Du, M., Guo, B., & Jia, D. (2010) · Polymer International · doi:10.1002/pi.2754 · Cited by 709
Anthony, J. W. (1990) · Medical Entomology and Zoology · Cited by 577
Halloysite Nanotubes as Biomimetic Nanoreactors
Shchukin, D. G., Sukhorukov, G. B., Price, R. R., et al. (2005) · Small · doi:10.1002/smll.200400120 · Cited by 387
Clay nanotubes for corrosion inhibitor encapsulation: release control with end stoppers
Abdullayev, E., & LVOV, Y. M. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm00810a · Cited by 285
Properties of halloysite nanotube–epoxy resin hybrids and the interfacial reactions in the systems
Liu, M., Guo, B., Du, M., Cai, X., & Jia, D. (2007) · Nanotechnology · doi:10.1088/0957-4484/18/45/455703 · Cited by 275
Order–Disorder in Clay Mineral Structures
Brindley, G. W. (2015) · Mineralogical Society of Great Britain and Ireland eBooks · doi:10.1180/mono-5.2 · Cited by 238
Halloysite nanotubes as a novel β-nucleating agent for isotactic polypropylene
Liu, M., Guo, B., Du, M., et al. (2009) · Polymer · doi:10.1016/j.polymer.2009.04.052 · Cited by 216
Surface Properties of Allophane, Halloysite, and Imogolite
Theng, B. K. G., Russell, M. A., Churchman, G. J., et al. (1982) · Clays and Clay Minerals · doi:10.1346/ccmn.1982.0300209 · Cited by 191
Introduction to mineral sciences
Downs, J. W. (1993) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(93)90207-d · Cited by 177
Stability of Aqueous Suspensions of Titanate Nanotubes
Bavykin, D. V., Friedrich, J. M., Lapkin, A. A., et al. (2006) · Chemistry of Materials · doi:10.1021/cm0521875 · Cited by 169
Self-citationMachado, G. S., Castro, K. A. D. F., Wypych, F., et al. (2007) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2007.12.009 · Cited by 154
Liu, M., Guo, B., Zou, Q., et al. (2008) · Nanotechnology · doi:10.1088/0957-4484/19/20/205709 · Cited by 131
Infrared and infrared emission spectroscopic study of typical Chinese kaolinite and halloysite
Cheng, H., Frost, R. L., Yang, J. H., et al. (2010) · Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · doi:10.1016/j.saa.2010.08.039 · Cited by 105
Barrientos-Ramírez, S., Ramos–Fernández, E. V., Silvestre‐Albero, J., Sepúlveda‐Escribano, A., Pastor‐Blas, M. M., & González‐Montiel, A. (2008) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2008.08.015 · Cited by 101
The first biopolymer-wrapped non-carbon nanotubes
Shamsi, M. H., & Geckeler, K. E. (2008) · Nanotechnology · doi:10.1088/0957-4484/19/7/075604 · Cited by 93
Equilibrium and kinetics of 5-aminosalicylic acid adsorption by halloysite
Viseras, M.-T., Aguzzi, C., Cerezo, P., et al. (2007) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2007.03.033 · Cited by 87
Raman Microprobe Spectroscopy of Halloysite
Frost, R. L., & Shurvell, H. F. (1997) · Clays and Clay Minerals · doi:10.1346/ccmn.1997.0450107 · Cited by 84
Reactions and clustering of water with silica surface
Ma, Y., Foster, A. S., & Nieminen, R. M. (2005) · The Journal of Chemical Physics · doi:10.1063/1.1878652 · Cited by 78
Wang, A., Kang, F., Huang, Z., et al. (2007) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2007.04.021 · Cited by 71
Experimental soil acidification
Dubíková, M., Cambier, P., Šucha, V., et al. (2002) · Applied Geochemistry · doi:10.1016/s0883-2927(01)00081-6 · Cited by 57
Study of Natural Halloysite from the Dragon Mine, Utah (USA)
García, F. J., García-Rodriguez, S., Kalytta, A., et al. (2009) · Zeitschrift für anorganische und allgemeine Chemie · doi:10.1002/zaac.200900076 · Cited by 56
Hydrothermal Synthesis of Kaolinite and its Formation Mechanism
Ryu, K., Jang, Y.-N., & Chae, S.-C. (2010) · Clays and Clay Minerals · doi:10.1346/ccmn.2010.0580104 · Cited by 34
Halloysite-Kaolinite Transformation at Room Temperature
Iglesia, Á. L., & Galan, E. (1975) · Clays and Clay Minerals · doi:10.1346/ccmn.1975.0230205 · Cited by 30
Thermal Stability of Halloysite by High-Pressure Differential Thermal Analysis
Johnson, S. L., Guggenheim, S., & van Groos, A. F. K. (1990) · Clays and Clay Minerals · doi:10.1346/ccmn.1990.0380503 · Cited by 29
Intercalation of Salts in Halloysite
Carr, R. M., Chaikum, N., & Patterson, N. (1978) · Clays and Clay Minerals · doi:10.1346/ccmn.1978.0260210 · Cited by 28
Nonlinear optics of nontoxic nanomaterials
Yelleswarapu, C. S., Gu, G., Abdullayev, E., et al. (2009) · Optics Communications · doi:10.1016/j.optcom.2009.10.001 · Cited by 27
Fu, Y., Zhang, L., & Zheng, J. (2005) · Journal of Nanoscience and Nanotechnology · doi:10.1166/jnn.2005.083 · Cited by 25
Research works printed but not linked: 1
- Robbie R A, 1979, US Geol. Surv. Bull., 1452, 456
Cited by
Sorted by citations
Osteogenesis Improvement of Gelatin-Based Nanocomposite Scaffold by Loading Zoledronic Acid
Abdulahy, S. B., Esmaeili Bidhendi, M., Vaezi, M. R., & Moosazadeh Moghaddam, M. (2022) · Frontiers in Bioengineering and Biotechnology · doi:10.3389/fbioe.2022.890583 · Cited by 13
“The location of this peak has not changed due to the scaffolding production process, which indicates that the HNT layers do not change and that the HNT and gelatin do not intercalate (White et al., 2012).”
Background
Metadata
- Authors
- White, R. D., Bavykin, D. V., & Walsh, F. C.
- Affiliations
- University of Southampton (GB)
- ORCID
- Bavykin, Dmitry V
- Venue
- Nanotechnology
- Publisher
- IOP Publishing
- Published
- 2012-01-17
- Volume
- 23
- Issue
- 6
- Pages
- 065705
- ISSN
- 0957-4484 (ISSN-L)
- 1361-6528
- OpenAlex
- W1972199881
- Cited by
- 185
- References
- 35
- Citations by year
- 2026: 9 · 2025: 6 · 2024: 22 · 2023: 12 · 2022: 16 · 2021: 18 · 2020: 23 · 2019: 17 · 2018: 10 · 2017: 13 · 2016: 12 · 2015: 12 · 2014: 7 · 2013: 3 · 2012: 5
- FWCI
- 3.49
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Nanotechnology (publishedVersion)
- PubMed (publishedVersion)
- ePrints Soton (University of Southampton) (acceptedVersion)
- Funders
- Engineering and Physical Sciences Research Council (EP/F044445/1)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Clay minerals and soil interactions
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer Nanocomposites and Properties
- Physical Sciences › Materials Science › Materials Chemistry › Layered Double Hydroxides Synthesis and Applications
- Keywords
- halloysite nanotubes, nanotube stability, dissolution, sulfuric acid, sodium hydroxide, silica nanoparticles, structural change
- MeSH terms
- Clay, Acids, Alkalies, Aluminum Silicates, Suspensions, Water, Nanotubes
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
