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Germanene: a novel two-dimensional germanium allotrope akin to graphene and silicene

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Dávila, M E, Xian, L, Cahangirov, S, Rubio, A, Le Lay, G·2014·New Journal of Physics

Abstract

We have grown an atom-thin, ordered, two-dimensional multi-phase film in situ through germanium molecular beam epitaxy using a gold (111) surface as a substrate. Its growth is similar to the formation of silicene layers on silver (111) templates. One of the phases, forming large domains, as observed in scanning tunneling microscopy, shows a clear, nearly flat, honeycomb structure. Thanks to thorough synchrotron radiation core-level spectroscopy measurements and advanced density functional theory calculations we can identify it as a √3 × √3 R (30°) germanene layer in conjunction with a √7 × √7 R (19.1°) Au(111) supercell, presenting compelling evidence of the synthesis of the germanium-based cousin of graphene on gold.

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Metadata

Authors
Dávila, M. E., Xian, L., Cahangirov, S., Rubio, A., & Le Lay, G.
Venue
New Journal of Physics
Published
2014-09-09
Volume
16
Issue
9
Pages
095002
ISSN
1367-2630 (ISSN-L)
OpenAlex
W2031985211
Cited by
1,601
References
0
FWCI
65.07
Type
journal article
Language
en
Open access
gold

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Dávila, M. E., Xian, L., Cahangirov, S., Rubio, A., & Le Lay, G. (2014). Germanene: a novel two-dimensional germanium allotrope akin to graphene and silicene. New Journal of Physics. https://doi.org/10.1088/1367-2630/16/9/095002

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