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The electronic properties of tetrahedral intermetallic compounds I. Charge distribution
Abstract
A discussion is commenced in which the electronic properties of tetrahedral intermetallic compounds are described in terms of localized molecular-orbital bonds. The correct definitions of covalency and polarity of these bonds are linked with the netionicity of the atoms of the crystal. Detailed non-empirical calculations of boron nitride provide a description of the bonds, and associated formal charges. An alternative simple but partially self-consistent analysis is presented whereby the coefficients in the simple molecular-orbital description may be found semi-empirically. The charges thus predicted agree well with those calculated by the earlier non-empirical method, and also with such experimental values as are available.
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Citations
Cited by
Semiconducting and other major properties of gallium arsenide
Blakemore, J. S. (1982) · Journal of Applied Physics · doi:10.1063/1.331665 · Cited by 2,503
Semiconductor crystallites: a class of large molecules
Steigerwald, M. L., & Brus, L. E. (1990) · Accounts of Chemical Research · doi:10.1021/ar00174a003 · Cited by 992
Metadata
- Authors
- Coulson, C. A., Rèdei, L. B., & Stocker, D.
- Venue
- Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Publisher
- The Royal Society
- Published
- 1962-11-27
- Volume
- 270
- Issue
- 1342
- Pages
- 357-372
- ISSN
- 0080-4630 (ISSN-L)
- 2053-9169
- OpenAlex
- W2051844798
- Cited by
- 201
- References
- 0
- FWCI
- 1.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: The electronic properties of tetrahedral intermetallic compounds I. Charge distribution. https://app.cochat.ai/papers/10.1098/rspa.1962.0229
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- Coulson, C. A., Rèdei, L. B., & Stocker, D. (1962). The electronic properties of tetrahedral intermetallic compounds I. Charge distribution. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences. https://doi.org/10.1098/rspa.1962.0229
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