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Optical studies of the 1.945 eV vibronic band in diamond

Davies, G., Hamer, M. F.·1976·Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences

Abstract

The 1.945eV band is the dominant end product of annealing radiation damage in diamonds containing isolated substitutional nitrogen atoms. In this paper uniaxial stress experiments are described which show the band to be a transition between A1 (ground) and E (excited) electronic states of a trigonal centre, the E state being coupled predominantly to A1 modes of vibration. Annealing experiments suggest that the centre is either a substitutional nitrogen atom plus an interstitial nitrogen atom, or a substitutional nitrogen atom plus a vacancy. Small differences between the luminescence and absorption bands are shown to be consistent with the double minima vibrational potential of the nitrogenvacancy model.

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Metadata

Authors
Davies, G., & Hamer, M. F.
Venue
Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences
Published
1976-02-24
Volume
348
Issue
1653
Pages
285-298
ISSN
  • 0080-4630 (ISSN-L)
  • 2053-9169
OpenAlex
W1985809477
Cited by
674
References
0
FWCI
2.42
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Optical studies of the 1.945 eV vibronic band in diamond. https://app.cochat.ai/papers/10.1098/rspa.1976.0039
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Davies, G., & Hamer, M. F. (1976). Optical studies of the 1.945 eV vibronic band in diamond. Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences. https://doi.org/10.1098/rspa.1976.0039

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.