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Cited by 261

The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.

Heterofunctionalization catalysis with organometallic complexes of calcium, strontium and barium

Open access
Barrett, Anthony G. M., Crimmin, Mark R., Hill, Michael S., Procopiou, Panayiotis A.·2010·Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences

Abstract

Despite the routine employment of Grignard reagents and Hauser bases as stoichiometric carbanion reagents in organic and inorganic synthesis, a defined reaction chemistry encompassing the heavier elements of Group II (M = Ca, Sr and Ba) has, until recently, remained unreported. This article provides details of the recent progress in heavier Group II catalysed small molecule transformations mediated by well-defined heteroleptic and homoleptic complexes of the form LMX or MX 2 ; where L is a mono-anionic ligand and X is a reactive σ-bonded substituent. The intra- and intermolecular heterofunctionalization (hydroamination, hydrophosphination, hydrosilylation and hydrogenation) of alkenes, alkynes, dienes, carbodiimides, isocyanates and ketones is discussed.

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Crossref · 10.1098/rspa.2009.0558

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Metadata

Authors
Barrett, A. G. M., Crimmin, M. R., Hill, M. S., & Procopiou, P. A.
Venue
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences
Published
2010-01-25
Volume
466
Issue
2116
Pages
927-963
ISSN
  • 1364-5021 (ISSN-L)
  • 1471-2946
OpenAlex
W2127703951
Cited by
261
References
2
FWCI
13.73
Type
journal article
Language
en
Open access
hybrid

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CoChat. (2026). Citation check: Heterofunctionalization catalysis with organometallic complexes of calcium, strontium and barium. https://app.cochat.ai/papers/10.1098/rspa.2009.0558
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Barrett, A. G. M., Crimmin, M. R., Hill, M. S., & Procopiou, P. A. (2010). Heterofunctionalization catalysis with organometallic complexes of calcium, strontium and barium. Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences. https://doi.org/10.1098/rspa.2009.0558

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