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Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond
Abstract
Raman spectroscopy is a standard characterization technique for any carbon system. Here we review the Raman spectra of amorphous, nanostructured, diamond-like carbon and nanodiamond. We show how to use resonant Raman spectroscopy to determine structure and composition of carbon films with and without nitrogen. The measured spectra change with varying excitation energy. By visible and ultraviolet excitation measurements, the G peak dispersion can be derived and correlated with key parameters, such as density, sp(3) content, elastic constants and chemical composition. We then discuss the assignment of the peaks at 1150 and 1480 cm(-1) often observed in nanodiamond. We review the resonant Raman, isotope substitution and annealing experiments, which lead to the assignment of these peaks to trans-polyacetylene.
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Cited by
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Lee, H., Kim, H.-I., Weon, S., Choi, W., Hwang, Y. S., Seo, J., Lee, C., & Kim, J.-H. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.6b02079 · Cited by 688
Borodko, Y., Lee, H. S., Joo, S. H., Zhang, Y., & Somorjai, G. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp909008z · Cited by 113
Impact shock origin of diamonds in ureilite meteorites
Nestola, F., Goodrich, C. A., Morana, M., Barbaro, A., Jakubek, R. S., Christ, O., Brenker, F. E., Domeneghetti, M. C., Dalconi, M. C., Alvaro, M., et al. (2020) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1919067117 · Cited by 58
Mirjalili, A., Dong, B., Pena, P., Ozkan, C. S., & Ozkan, M. (2020) · Energy Storage · doi:10.1002/est2.201 · Cited by 46
Thoma, M., Lin, W., Hoffmann, E., Sattes, M.-M., Segets, D., Damm, C., & Peukert, W. (2018) · Langmuir · doi:10.1021/acs.langmuir.8b02726 · Cited by 37
Metadata
- Authors
- Ferrari, A. C., & Robertson, J.
- Venue
- Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences
- Publisher
- The Royal Society
- Published
- 2004-09-28
- Volume
- 362
- Issue
- 1824
- Pages
- 2477-2512
- ISSN
- 1364-503X (ISSN-L)
- 1471-2962
- OpenAlex
- W2133061058
- Cited by
- 2,689
- References
- 0
- FWCI
- 9.79
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ferrari, A. C., & Robertson, J. (2004). Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond. Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences. https://doi.org/10.1098/rsta.2004.1452
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