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Theory of the Role of Covalence in the Perovskite-Type Manganites[La, M(II)]MnO3
Open accessAbstract
The theory of semicovalent exchange is reviewed and applied to the perovskite-type manganites $[\mathrm{La}, M(\mathrm{II})]\mathrm{Mn}{\mathrm{O}}_{3}$. With the hypothesis of covalent and semicovalent bonding between the oxygen and manganese ions plus the mechanism of double exchange, detailed qualitative predictions are made about the magnetic lattice, the crystallographic lattice, the electrical resistivity, and the Curie temperature as functions of the fraction of ${\mathrm{Mn}}^{4+}$ present. These predictions are found to be in accord with recent findings from neutron-diffraction and x-ray data as well as with the earlier experiments on this system by Jonker and van Santen.
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Cited by
Superexchange interaction and symmetry properties of electron orbitals
Kanamori, J. (1959) · Journal of Physics and Chemistry of Solids · doi:10.1016/0022-3697(59)90061-7 · Cited by 3,402
Direct Observation of Charge and Orbital Ordering inLa0.5Sr1.5MnO4
Murakami, Y., Kawada, H., Kawata, H., Tanaka, M., Arima, T., Moritomo, Y., & Tokura, Y. (1998) · Physical Review Letters · doi:10.1103/physrevlett.80.1932 · Cited by 554
Progress in perovskite nickelate research
Catalan, G. (2008) · Phase Transitions · doi:10.1080/01411590801992463 · Cited by 451
Recent progress on 2D magnets: Fundamental mechanism, structural design and modification
Jiang, X., Liu, Q., Xing, J., Liu, N., Guo, Y., Liu, Z., & Zhao, J. (2021) · Applied Physics Reviews · doi:10.1063/5.0039979 · Cited by 445
Metzger, R. M. (2015) · Chemical Reviews · doi:10.1021/cr500459d · Cited by 380
Metadata
- Authors
- Goodenough, J. B.
- Venue
- Physical Review
- Publisher
- American Physical Society (APS)
- Published
- 1955-10-15
- Volume
- 100
- Issue
- 2
- Pages
- 564-573
- ISSN
- 0031-899X (ISSN-L)
- OpenAlex
- W2005355114
- Cited by
- 4,498
- References
- 0
- FWCI
- 10.45
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Goodenough, J. B. (1955). Theory of the Role of Covalence in the Perovskite-Type Manganites[La, M(II)]MnO3. Physical Review. https://doi.org/10.1103/physrev.100.564
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