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First-Order Raman Effect in Wurtzite-Type Crystals
Abstract
First-order Raman scattering from BeO, ZnO, ZnS, and CdS, all having the wurtzite structure (${C}_{6v}$), has been investigated. A discussion of the effects of the competition between the long-range electrostatic forces and the short-range forces due to anisotropy in the interatomic force constants on the vibrational spectrum has been included. A series of scattering diagrams are presented showing the geometrical arrangements necessary to observe all the $k=0$ phonons for this type of crystal structure. In BeO the ${E}_{2}$ mode was resolved from the transverse modes for the first time. The assignments of the ${E}_{2}$ modes in ZnS differ from previous investigations. From absolute intensity measurements, electro-optic coefficients for BeO, ZnO, and CdS were determined.
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Cited by
Phonon dispersion and Raman scattering in hexagonal GaN and AlN
Davydov, V. Y., Kitaev, Y. E., Goncharuk, I. N., Smirnov, A. N., Graul, J., Semchinova, O., Uffmann, D., Smirnov, M. B., Mirgorodsky, A. P., & Evarestov, R. A. (1998) · Physical Review B · doi:10.1103/physrevb.58.12899 · Cited by 836
Properties of GaN and related compounds studied by means of Raman scattering
Harima, H. (2002) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/14/38/201 · Cited by 699
Fast Synthesis of ZnO Nanostructures by Laser-Induced Decomposition of Zinc Acetylacetonate
Fauteux, C., Longtin, R., Pegna, J., & Therriault, D. (2007) · Inorganic Chemistry · doi:10.1021/ic700915z · Cited by 63
Metadata
- Authors
- Arguello, C. A., Rousseau, D. L., & Porto, S. P. S.
- Venue
- Physical Review
- Publisher
- American Physical Society (APS)
- Published
- 1969-05-15
- Volume
- 181
- Issue
- 3
- Pages
- 1351-1363
- ISSN
- 0031-899X (ISSN-L)
- OpenAlex
- W2042243397
- Cited by
- 1,053
- References
- 0
- FWCI
- 9.23
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: First-Order Raman Effect in Wurtzite-Type Crystals. https://app.cochat.ai/papers/10.1103/physrev.181.1351
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- Arguello, C. A., Rousseau, D. L., & Porto, S. P. S. (1969). First-Order Raman Effect in Wurtzite-Type Crystals. Physical Review. https://doi.org/10.1103/physrev.181.1351
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