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Soliton excitations in polyacetylene

Su, W. P., Schrieffer, J. R., Heeger, A. J.·1980·Physical Review B

Abstract

A theoretical analysis of the excitation spectrum of long-chain polyenes is presented. Because of the twofold degeneracy of the ground state of the dimerized chain, elementary excitations corresponding to topological solitons are obtained. The solitons can have three charge states $Q=0$. $\ifmmode\pm\else\textpm\fi{}e$. The neutral soliton has spin one-half while the charged solitons have spin zero. One electronic state is localized at the gap center for each soliton or antisoliton present. The soliton's energy of formation, length, mass, activation energy for motion, and electronic properties are calculated. These results are compared with experiment.

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Metadata

Authors
Su, W. P., Schrieffer, J. R., & Heeger, A. J.
Venue
Physical Review B
Published
1980-08-15
Volume
22
Issue
4
Pages
2099-2111
ISSN
0163-1829 (ISSN-L)
OpenAlex
W2062089197
Cited by
3,143
References
0
FWCI
102.74
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Soliton excitations in polyacetylene. https://app.cochat.ai/papers/10.1103/physrevb.22.2099
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Su, W. P., Schrieffer, J. R., & Heeger, A. J. (1980). Soliton excitations in polyacetylene. Physical Review B. https://doi.org/10.1103/physrevb.22.2099

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