The DOI matches its Crossref record; 28 of the 28 references it cites were found in a registry or an index.
Study of theL23edges in the3dtransition metals and their oxides by electron-energy-loss spectroscopy with comparisons to theory
Abstract
Excitations of the $2p$ subshell in the $3d$ transition metals and their oxides have been studied by inelastic scattering of 75-keV electrons. The ${L}_{23}$ "white lines" which arise from dipole transitions to unoccupied $d$ states have been investigated in terms of their threshold energies, widths, and intensity ratios. Shifts in the ${L}_{3}$ threshold energy between the metal and oxide are different from the chemical shifts measured by x-ray photoemission spectroscopy and this suggests the importance of relaxation effects. Single-particle calculations for the ${L}_{3}$ spectra are also discussed. Measured ${L}_{3}$ linewidths are generally larger than those predicted by suitably broadened theory. A variation from the statistical ${L}_{3}$-to-${L}_{2}$ white-line intensity ratio of 2:1 has been observed across the $3d$ transition row, with values ranging between 0.8:1 for Ti to 5:1 for FeO. This behavior appears to be associated with the white lines since Cu with a filled $3d$ band exhibits the statistical results. It is suggested that the anomalous ratios may be explained by a breakdown of $j\ensuremath{-}j$ coupling caused by an exchange mechanism. Finally, the extended x-ray absorption fine-structure-type structure extending several hundred eV above the white lines is analyzed for Cr to provide the radial distribution function.
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Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Study of theKedges of3dtransition metals in pure and oxide form by x-ray-absorption spectroscopy
Grunes, L. A. (1983) · Physical Review B · doi:10.1103/physrevb.27.2111 · Cited by 494
Self-citationAtomic-resolution imaging of oxidation states in manganites
Varela, M., Oxley, M. P., Luo, W., Tao, J., Watanabe, M., Lupini, A. R., Pantelides, S. T., & Pennycook, S. J. (2009) · Physical Review B · doi:10.1103/physrevb.79.085117 · Cited by 320
Observation of electric-field induced Ni filament channels in polycrystalline NiOx film
Park, G.-S., Li, X.-S., Kim, D.-C., Jung, R.-J., Lee, M.-J., & Seo, S. (2007) · Applied Physics Letters · doi:10.1063/1.2813617 · Cited by 238
Cavalca, F., Ferragut, R., Aghion, S., Eilert, A., Diaz-Morales, O., Liu, C., Koh, A. L., Hansen, T. W., Pettersson, L. G. M., & Nilsson, A. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b08278 · Cited by 123
Metadata
- Authors
- Leapman, R. D., Grunes, L. A., & Fejes, P. L.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1982-07-15
- Volume
- 26
- Issue
- 2
- Pages
- 614-635
- ISSN
- 0163-1829 (ISSN-L)
- OpenAlex
- W2073732618
- Cited by
- 699
- References
- 28
- FWCI
- 17.26
- Type
- journal article
- Language
- en
- Open access
- closed
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- Leapman, R. D., Grunes, L. A., & Fejes, P. L. (1982). Study of theL23edges in the3dtransition metals and their oxides by electron-energy-loss spectroscopy with comparisons to theory. Physical Review B. https://doi.org/10.1103/physrevb.26.614
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