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Comparison of x-ray absorption with x-ray photoemission of nickel dihalides and NiO
Open accessAbstract
High-resolution ${L}_{2}$,3 x-ray absorption data are presented for nickel dihalides and nickel oxide. The near-edge multiplet splitting is observed to decrease rapidly with decreasing anion electronegativity. This decrease is accompanied by an increase in a satellite feature. A detailed analysis of the data in terms of recently proposed many-body theories is presented and is shown to yield excellent agreement with experiment allowing a determination of the charge-transfer energy, the d-d Coulomb interaction, and the Ni d--anion p hybridization interaction. We show that the values obtained are in good agreement with those obtained from x-ray photoelectron spectroscopy even though the spectral shapes are strongly different. The difference in spectral shapes is shown to be due to the very different final states.
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Citations
Cited by
Multiplet effects in X-ray spectroscopy
Groot, F. D. (2005) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2004.03.018 · Cited by 788
X-ray absorption and dichroism of transition metals and their compounds
de Groot, F. M. F. (1994) · Journal of Electron Spectroscopy and Related Phenomena · doi:10.1016/0368-2048(93)02041-j · Cited by 677
Chen, J. G. (1997) · Surface Science Reports · doi:10.1016/s0167-5729(97)00011-3 · Cited by 620
Shen, Z.-X., & Dessau, D. S. (1995) · Physics Reports · doi:10.1016/0370-1573(95)80001-a · Cited by 598
Multiplet ligand-field theory using Wannier orbitals
Haverkort, M. W., Zwierzycki, M., & Andersen, O. K. (2012) · Physical Review B · doi:10.1103/physrevb.85.165113 · Cited by 444
Metadata
- Authors
- van der Laan, G., Zaanen, J., Sawatzky, G. A., Karnatak, R., & Esteva, J.-M.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1986-03-15
- Volume
- 33
- Issue
- 6
- Pages
- 4253-4263
- ISSN
- 0163-1829 (ISSN-L)
- OpenAlex
- W2013761935
- Cited by
- 369
- References
- 0
- FWCI
- 29.13
- Type
- journal article
- Language
- en
- Open access
- green
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- CoChat. (2026). Citation check: Comparison of x-ray absorption with x-ray photoemission of nickel dihalides and NiO. https://app.cochat.ai/papers/10.1103/physrevb.33.4253
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- van der Laan, G., Zaanen, J., Sawatzky, G. A., Karnatak, R., & Esteva, J.-M. (1986). Comparison of x-ray absorption with x-ray photoemission of nickel dihalides and NiO. Physical Review B. https://doi.org/10.1103/physrevb.33.4253
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