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Calculation of the band gap for small CdS and ZnS crystallites
Abstract
The tight-binding approximation and the recursion method are used to study the size dependence of the band gap for small CdS and ZnS crystallites (20--2500 atoms). Because of the lack of accurate experimental data, a simple model of the crystal is considered; one which has no dangling bonds and a symmetrical shape. It is then possible to have a good evaluation of the band gap, even for the largest crystallites. The optical-absorption spectra exhibit an excitonic peak; we determine the peak position from a simple evaluation of the binding energy. The results are compared with the results of other calculations based upon the effective-mass approximation and some experimental data.
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Citations
Cites
Quantum Theory of Cyclotron Resonance in Semiconductors: General Theory
Luttinger, J. M. (1956) · Physical Review · doi:10.1103/physrev.102.1030 · Cited by 2,199
Cited by
Semiconductor crystallites: a class of large molecules
Steigerwald, M. L., & Brus, L. E. (1990) · Accounts of Chemical Research · doi:10.1021/ar00174a003 · Cited by 992
Size-dependent band gap of colloidal quantum dots
Baskoutas, S., & Terzis, A. F. (2006) · Journal of Applied Physics · doi:10.1063/1.2158502 · Cited by 384
Growth Kinetics of Nanocrystalline ZnO Particles from Colloidal Suspensions
Wong, E. M., Bonevich, J. E., & Searson, P. C. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp982397n · Cited by 351
Quantum confinement effects in semiconductor clusters
Rama Krishna, M. V., & Friesner, R. A. (1991) · The Journal of Chemical Physics · doi:10.1063/1.461258 · Cited by 329
Metadata
- Authors
- Lippens, P. E., & Lannoo, M.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1989-05-15
- Volume
- 39
- Issue
- 15
- Pages
- 10935-10942
- ISSN
- 0163-1829 (ISSN-L)
- OpenAlex
- W2052491407
- Cited by
- 811
- References
- 1
- FWCI
- 15.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lippens, P. E., & Lannoo, M. (1989). Calculation of the band gap for small CdS and ZnS crystallites. Physical Review B. https://doi.org/10.1103/physrevb.39.10935
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