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Strong quantum-size effects in a layered semiconductor:MoS2nanoclusters
Abstract
High-quality, size-selected, nano-size (2--15 nm\ifmmode\pm\else\textpm\fi{}10%) clusters of ${\mathrm{MoS}}_{2}$ have been successfully grown inside inverse micellar cages and their optical properties have been studied. These clusters exhibit (1) large blueshifts in the optical-absorption features with decreasing cluster size due to quantum confinement, affording great tailorability in the absorption thresholds and (2) a demonstration of the crossover from bandlike (solid) to moleculelike spectra as the size of the clusters becomes smaller than that of the exciton in the bulk.
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Cited by
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
Chhowalla, M., Shin, H. S., Eda, G., Li, L.-J., Loh, K. P., & Zhang, H. (2013) · Nature Chemistry · doi:10.1038/nchem.1589 · Cited by 10,034
Kibsgaard, J., Chen, Z., Reinecke, B. N., & Jaramillo, T. F. (2012) · Nature Materials · doi:10.1038/nmat3439 · Cited by 3,234
Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials
Benck, J. D., Hellstern, T. R., Kibsgaard, J., Chakthranont, P., & Jaramillo, T. F. (2014) · ACS Catalysis · doi:10.1021/cs500923c · Cited by 1,617
Li, B., Jiang, L., Li, X., Ran, P., Zuo, P., Wang, A., Qu, L., Zhao, Y., Cheng, Z., & Lu, Y. (2017) · Scientific Reports · doi:10.1038/s41598-017-10632-3 · Cited by 358
Catalytic Properties of Single Layers of Transition Metal Sulfide Catalytic Materials
Chianelli, R. R., Siadati, M. H., De la Rosa, M. P., Berhault, G., Wilcoxon, J. P., Bearden, R., & Abrams, B. L. (2006) · Catalysis Reviews · doi:10.1080/01614940500439776 · Cited by 304
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Metadata
- Authors
- Wilcoxon, J. P., & Samara, G. A.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1995-03-15
- Volume
- 51
- Issue
- 11
- Pages
- 7299-7302
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W2001487342
- Cited by
- 227
- References
- 0
- FWCI
- 5.62
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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