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Efficient interchain photoluminescence in a high-electron-affinity conjugated polymer
Abstract
We report measurements of photoluminescence efficiency and time dependence in a high-electron-affinity cyano-substituted derivative of poly(p-phenylenevinylene). We find that the luminescence is much longer lived in solid films than in solutions and interpret this result as emission in the film being from an interchain excitation. These results suggest that intermolecular interactions are an important consideration in the design of highly luminescent conjugated polymers.
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Cited by
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Clarke, T. M., & Durrant, J. R. (2010) · Chemical Reviews · doi:10.1021/cr900271s · Cited by 2,372
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Penwell, S. B., Ginsberg, L. D. S., Noriega, R., & Ginsberg, N. S. (2017) · Nature Materials · doi:10.1038/nmat4975 · Cited by 52
Metadata
- Authors
- Samuel, I. D. W., Rumbles, G., & Collison, C. J.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1995-10-15
- Volume
- 52
- Issue
- 16
- Pages
- R11573-R11576
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W2082002840
- Cited by
- 239
- References
- 0
- FWCI
- 14.85
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Efficient interchain photoluminescence in a high-electron-affinity conjugated polymer. https://app.cochat.ai/papers/10.1103/physrevb.52.r11573
- The paper
- Samuel, I. D. W., Rumbles, G., & Collison, C. J. (1995). Efficient interchain photoluminescence in a high-electron-affinity conjugated polymer. Physical Review B. https://doi.org/10.1103/physrevb.52.r11573
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
