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Infrared reflectivity and lattice fundamentals in anataseTiO2s

Gonzalez, R. J., Zallen, R., Berger, H.·1997·Physical Review B

Abstract

Polarization-dependent far-infrared reflectivity measurements were carried out on single crystals of anatase ${\mathrm{TiO}}_{2}$ . The results were analyzed to yield the dielectric dispersion properties of anatase in the lattice fundamentals regime. The frequencies (in ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ ) of the transverse optical (TO) and longitudinal optical (LO) zone-center phonons were determined to be 367(755) for the TO (LO) of the ${\mathrm{A}}_{2\mathrm{u}}$ mode, 262(366) and 435(876) for the ${\mathrm{E}}_{\mathrm{u}}$ modes. The large TO-LO splittings were used to estimate effective charges.

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Metadata

Authors
Gonzalez, R. J., Zallen, R., & Berger, H.
Venue
Physical Review B
Published
1997-03-15
Volume
55
Issue
11
Pages
7014-7017
ISSN
  • 0163-1829 (ISSN-L)
  • 1095-3795
OpenAlex
W2031391170
Cited by
301
References
0
FWCI
2.81
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Infrared reflectivity and lattice fundamentals in anataseTiO2s. https://app.cochat.ai/papers/10.1103/physrevb.55.7014
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Gonzalez, R. J., Zallen, R., & Berger, H. (1997). Infrared reflectivity and lattice fundamentals in anataseTiO2s. Physical Review B. https://doi.org/10.1103/physrevb.55.7014

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