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Infrared reflectivity and lattice fundamentals in anataseTiO2s
Abstract
Polarization-dependent far-infrared reflectivity measurements were carried out on single crystals of anatase ${\mathrm{TiO}}_{2}$ . The results were analyzed to yield the dielectric dispersion properties of anatase in the lattice fundamentals regime. The frequencies (in ${\mathrm{cm}}^{\mathrm{\ensuremath{-}}1}$ ) of the transverse optical (TO) and longitudinal optical (LO) zone-center phonons were determined to be 367(755) for the TO (LO) of the ${\mathrm{A}}_{2\mathrm{u}}$ mode, 262(366) and 435(876) for the ${\mathrm{E}}_{\mathrm{u}}$ modes. The large TO-LO splittings were used to estimate effective charges.
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Cited by
Le Bahers, T., Rérat, M., & Sautet, P. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp409724c · Cited by 319
Ben Yahia, M., Lemoigno, F., Beuvier, T., Filhol, J.-S., Richard-Plouet, M., Brohan, L., & Doublet, M.-L. (2009) · The Journal of Chemical Physics · doi:10.1063/1.3130674 · Cited by 113
Yue, X., Li, H., Qiu, Y., Xiao, Z., Yu, X., Xue, C., & Xiang, J. (2021) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2021.122250 · Cited by 16
Metadata
- Authors
- Gonzalez, R. J., Zallen, R., & Berger, H.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1997-03-15
- Volume
- 55
- Issue
- 11
- Pages
- 7014-7017
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W2031391170
- Cited by
- 301
- References
- 0
- FWCI
- 2.81
- Type
- journal article
- Language
- en
- Open access
- closed
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- Gonzalez, R. J., Zallen, R., & Berger, H. (1997). Infrared reflectivity and lattice fundamentals in anataseTiO2s. Physical Review B. https://doi.org/10.1103/physrevb.55.7014
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