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Near-field optical spectroscopy of individual surface-plasmon modes in colloid clusters

Markel, V. A., Shalaev, V. M., Zhang, P., Huynh, W., Tay, L., Haslett, T. L., Moskovits, M.·1999·Physical Review B

Abstract

Local spectra of self-affine clusters of silver colloid particles recorded with subwavelength resolution by near-field spectroscopy are reported. Spectra were also simulated computationally. The observed and calculated near-field spectra consist of several resonances with highly location-dependent frequencies. The most highly resolved of these resonances correspond to individual surface plasmon (SP) normal modes. All of these features are only observable in the near field. Both theory and experiment also show that when excited by light in the SP region of the spectrum, the field-intensity distribution in the near field is very heterogeneous with most of the excitation concentrated in ``hot spots'' on the cluster surface that are strongly excitation-wavelength dependent. This field-intensity localization provides a rationale for recently reported surface-enhanced Raman enhancements in excess of ${10}^{10}.$

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Metadata

Authors
Markel, V. A., Shalaev, V. M., Zhang, P., Huynh, W., Tay, L., Haslett, T. L., & Moskovits, M.
Venue
Physical Review B
Published
1999-04-15
Volume
59
Issue
16
Pages
10903-10909
ISSN
  • 0163-1829 (ISSN-L)
  • 1095-3795
OpenAlex
W2091848633
Cited by
298
References
0
FWCI
14.71
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Near-field optical spectroscopy of individual surface-plasmon modes in colloid clusters. https://app.cochat.ai/papers/10.1103/physrevb.59.10903
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Markel, V. A., Shalaev, V. M., Zhang, P., Huynh, W., Tay, L., Haslett, T. L., & Moskovits, M. (1999). Near-field optical spectroscopy of individual surface-plasmon modes in colloid clusters. Physical Review B. https://doi.org/10.1103/physrevb.59.10903

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