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Near-field optical spectroscopy of individual surface-plasmon modes in colloid clusters
Abstract
Local spectra of self-affine clusters of silver colloid particles recorded with subwavelength resolution by near-field spectroscopy are reported. Spectra were also simulated computationally. The observed and calculated near-field spectra consist of several resonances with highly location-dependent frequencies. The most highly resolved of these resonances correspond to individual surface plasmon (SP) normal modes. All of these features are only observable in the near field. Both theory and experiment also show that when excited by light in the SP region of the spectrum, the field-intensity distribution in the near field is very heterogeneous with most of the excitation concentrated in ``hot spots'' on the cluster surface that are strongly excitation-wavelength dependent. This field-intensity localization provides a rationale for recently reported surface-enhanced Raman enhancements in excess of ${10}^{10}.$
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Citations
Cited by
Ghosh, S. K., & Pal, T. (2007) · Chemical Reviews · doi:10.1021/cr0680282 · Cited by 2,782
Analytical applications of Raman spectroscopy
Kudelski, A. (2008) · Talanta · doi:10.1016/j.talanta.2008.02.042 · Cited by 455
Single molecule analysis by surfaced-enhanced Raman scattering
Pieczonka, N. P. W., & Aroca, R. F. (2008) · Chemical Society Reviews · doi:10.1039/b709739p · Cited by 451
Persistent misconceptions regarding SERS
Moskovits, M. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp44030j · Cited by 295
Self-citationSurface-enhanced Raman spectroscopy at single-molecule scale and its implications in biology
Wang, Y., & Irudayaraj, J. (2013) · Philosophical Transactions of the Royal Society B: Biological Sciences · doi:10.1098/rstb.2012.0026 · Cited by 125
Metadata
- Authors
- Markel, V. A., Shalaev, V. M., Zhang, P., Huynh, W., Tay, L., Haslett, T. L., & Moskovits, M.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1999-04-15
- Volume
- 59
- Issue
- 16
- Pages
- 10903-10909
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W2091848633
- Cited by
- 298
- References
- 0
- FWCI
- 14.71
- Type
- journal article
- Language
- en
- Open access
- closed
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- Markel, V. A., Shalaev, V. M., Zhang, P., Huynh, W., Tay, L., Haslett, T. L., & Moskovits, M. (1999). Near-field optical spectroscopy of individual surface-plasmon modes in colloid clusters. Physical Review B. https://doi.org/10.1103/physrevb.59.10903
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