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Charge- and energy-transfer processes at polymer/polymer interfaces: A joint experimental and theoretical study
Abstract
When an exciton approaches the interface between two conjugated polymers, either energy or charge transfer can take place. We present a detailed experimental investigation of these processes in various binary polymer systems. The results are interpreted in the context of quantum-chemical calculations that provide estimates of the relative energies of intrachain versus interchain excited states in pairs of various PPV-related chains. In particular, we show that charge-transfer occurs at the interface between MEH-PPV and a cyano-substituted PPV derivative, whereas energy transfer takes place at the interface of PPV with the same cyano-substituted polymer.
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Cited by
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Clarke, T. M., & Durrant, J. R. (2010) · Chemical Reviews · doi:10.1021/cr900271s · Cited by 2,372
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Mishra, A., & Bäuerle, P. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201102326 · Cited by 1,816
Zhao, G.-J., & Han, K.-L. (2007) · The Journal of Physical Chemistry A · doi:10.1021/jp0719659 · Cited by 414
Huang, X., Zhu, C., Zhang, S., Li, W., Guo, Y., Zhan, X., Liu, Y., & Bo, Z. (2008) · Macromolecules · doi:10.1021/ma801407u · Cited by 150
Metadata
- Authors
- Halls, J. J. M., Cornil, J., dos Santos, D. A., Silbey, R., Hwang, D.-H., Holmes, A. B., Brédas, J. L., & Friend, R. H.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1999-08-15
- Volume
- 60
- Issue
- 8
- Pages
- 5721-5727
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W2008979257
- Cited by
- 292
- References
- 0
- FWCI
- 8.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Halls, J. J. M., Cornil, J., dos Santos, D. A., Silbey, R., Hwang, D.-H., Holmes, A. B., Brédas, J. L., & Friend, R. H. (1999). Charge- and energy-transfer processes at polymer/polymer interfaces: A joint experimental and theoretical study. Physical Review B. https://doi.org/10.1103/physrevb.60.5721
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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