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Size effects in the structural phase transition ofVO2nanoparticles
Abstract
We have observed size effects in the structural phase transition of submicron vanadium dioxide precipitates in silica. The ${\mathrm{VO}}_{2}$ nanoprecipitates are produced by the stoichiometric coimplantation of vanadium and oxygen and subsequent thermal processing. The observed size dependence in the transition temperature and hysteresis loops of the semiconductor-to-metal phase transition in ${\mathrm{VO}}_{2}$ is described in terms of heterogeneous nucleation statistics with a phenomenological approach in which the density of nucleating defects is a power function of the driving force.
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Citations
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Cited by
Oxide Electronics Utilizing Ultrafast Metal-Insulator Transitions
Yang, Z., Ko, C., & Ramanathan, S. (2011) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-062910-100347 · Cited by 1,020
Memory effects in complex materials and nanoscale systems
Pershin, Y. V., & Di Ventra, M. (2011) · Advances In Physics · doi:10.1080/00018732.2010.544961 · Cited by 823
Metal-insulator phase transition in aVO2thin film observed with terahertz spectroscopy
Jepsen, P. U., Fischer, B. M., Thoman, A., Helm, H., Suh, J. Y., Lopez, R., & Haglund, R. F. (2006) · Physical Review B · doi:10.1103/physrevb.74.205103 · Cited by 396
Self-citationLi, S.-Y., Niklasson, G. A., & Granqvist, C. G. (2010) · Journal of Applied Physics · doi:10.1063/1.3487980 · Cited by 298
Metadata
- Authors
- Lopez, R., Haynes, T. E., Boatner, L. A., Feldman, L. C., & Haglund, R. F.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2002-06-11
- Volume
- 65
- Issue
- 22
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W1972526400
- Cited by
- 379
- References
- 6
- FWCI
- 6.32
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lopez, R., Haynes, T. E., Boatner, L. A., Feldman, L. C., & Haglund, R. F. (2002). Size effects in the structural phase transition ofVO2nanoparticles. Physical Review B. https://doi.org/10.1103/physrevb.65.224113
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