The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Continuum generation from single gold nanostructures through near-field mediated intraband transitions
Abstract
A broad visible and infrared photoluminescence continuum is detected from surface-plasmon-enhanced transitions in gold nanostructures. We find that the ratio of generated infrared to visible emission is much stronger for gold nanostructures than for smooth gold films. While visible emission is well explained by interband transitions of d-band electrons into the conduction band and subsequent radiative recombination, the strong infrared emission cannot be accounted for by the same mechanism. We propose that the infrared emission is generated by intraband transitions mediated by the strongly confined fields near metal nanostructures (localized surface plasmons). These fields possess wave numbers that are comparable to the wave numbers of electrons in the metal, and the associated field gradients give rise to higher-order multipolar transitions. We compare photoluminescence spectra for single gold spheres, smooth and rough gold films, and sharp gold tips and demonstrate that the infrared signal is only present for surfaces with nanometer-scale roughness.
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Cites
Optical Constants of the Noble Metals
Johnson, P. B., & Christy, R. W. (1972) · Physical Review B · doi:10.1103/physrevb.6.4370 · Cited by 20,094
Beiträge zur Optik trüber Medien, speziell kolloidaler Metallösungen
Mie, G. (1908) · Annalen der Physik · doi:10.1002/andp.19083300302 · Cited by 11,537
Cited by
Mühlschlegel, P., Eisler, H.-J., Martin, O. J. F., Hecht, B., & Pohl, D. W. (2005) · Science · doi:10.1126/science.1111886 · Cited by 2,115
Optical Frequency Mixing at Coupled Gold Nanoparticles
Danckwerts, M., & Novotny, L. (2007) · Physical Review Letters · doi:10.1103/physrevlett.98.026104 · Cited by 522
Self-citationSpectroscopic Mode Mapping of Resonant Plasmon Nanoantennas
Ghenuche, P., Cherukulappurath, S., Taminiau, T. H., van Hulst, N. F., & Quidant, R. (2008) · Physical Review Letters · doi:10.1103/physrevlett.101.116805 · Cited by 391
Righini, M., Ghenuche, P., Cherukulappurath, S., Myroshnychenko, V., García de Abajo, F. J., & Quidant, R. (2009) · Nano Letters · doi:10.1021/nl803677x · Cited by 344
Shangguan, W., Liu, Q., Wang, Y., Sun, N., Liu, Y., Zhao, R., Li, Y., Wang, C., & Zhao, J. (2022) · Nature Communications · doi:10.1038/s41467-022-31474-2 · Cited by 332
Metadata
- Authors
- Beversluis, M. R., Bouhelier, A., & Novotny, L.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2003-09-30
- Volume
- 68
- Issue
- 11
- ISSN
- 0163-1829 (ISSN-L)
- 1095-3795
- OpenAlex
- W1976098525
- Cited by
- 620
- References
- 2
- FWCI
- 11.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Beversluis, M. R., Bouhelier, A., & Novotny, L. (2003). Continuum generation from single gold nanostructures through near-field mediated intraband transitions. Physical Review B. https://doi.org/10.1103/physrevb.68.115433
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