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Core-Electron Splittings and Hyperfine Fields in Transition-Metal Compounds
Abstract
$2s$ and $3s$ core-electron exchange splittings have been measured for a number of transition-metal compounds. It is found that the $2s$ splittings agree roughly with values from Hartree-Fock calculations, whereas measured $3s$ splittings are smaller by about a factor of 2. This discrepancy is tentatively linked to correlations connected with the hole produced by the photoelectric process. A comparison of exchange splittings with hyperfine fields in spin-only compounds suggests a close relationship between these two properties.
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Citations
Cited by
HAWKING, S. W. (1974) · Nature · doi:10.1038/248030a0 · Cited by 5,669
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ON THE ROLE OF CHAOS IN THE AdS/CFT CONNECTION
RAMA, S. K., & SATHIAPALAN, B. (1999) · Modern Physics Letters A · doi:10.1142/s0217732399002777 · Cited by 59
CORICHI, A., & SUDARSKY, D. (2002) · Modern Physics Letters A · doi:10.1142/s0217732302007843 · Cited by 12
Metadata
- Authors
- Hüfner, S., & Wertheim, G. K.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1973-03-15
- Volume
- 7
- Issue
- 6
- Pages
- 2333-2336
- ISSN
- 0556-2805 (ISSN-L)
- OpenAlex
- W1996860404
- Cited by
- 158
- References
- 0
- FWCI
- 11.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Core-Electron Splittings and Hyperfine Fields in Transition-Metal Compounds. https://app.cochat.ai/papers/10.1103/physrevb.7.2333
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- Hüfner, S., & Wertheim, G. K. (1973). Core-Electron Splittings and Hyperfine Fields in Transition-Metal Compounds. Physical Review B. https://doi.org/10.1103/physrevb.7.2333
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