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Cited by 297

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Properties of the quaternary half-metal-type Heusler alloyCo2Mn1−xFexSi

Open access
Balke, Benjamin, Fecher, Gerhard H., Kandpal, Hem C., Felser, Claudia, Kobayashi, Keisuke, Ikenaga, Eiji, Kim, Jung-Jin, Ueda, Shigenori·2006·Physical Review B

Abstract

This paper reports on the bulk properties of the quaternary Heusler alloy ${\mathrm{Co}}_{2}{\mathrm{Mn}}_{1\ensuremath{-}x}{\mathrm{Fe}}_{x}\mathrm{Si}$ with the Fe concentration $x=0,1∕2,1$. All samples, which were prepared by arc melting, exhibit $L{2}_{1}$ long-range order over the complete range of Fe concentration. The structural and magnetic properties of the ${\mathrm{Co}}_{2}{\mathrm{Mn}}_{1\ensuremath{-}x}{\mathrm{Fe}}_{x}\mathrm{Si}$ Heusler alloys were investigated by means of x-ray diffraction, high- and low-temperature magnetometry, M\"ossbauer spectroscopy, and differential scanning calorimetry. The electronic structure was explored by means of high-energy photoemission spectroscopy at about $8\phantom{\rule{0.3em}{0ex}}\mathrm{keV}$ photon energy. This ensures true bulk sensitivity of the measurements. The magnetization of the Fe-doped Heusler alloys is in agreement with the values of the magnetic moments expected for a Slater-Pauling-like behavior of half-metallic ferromagnets. The experimental findings are discussed on the basis of self-consistent calculations of the electronic and magnetic structure. To achieve good agreement with experiment, the calculations indicate that on-site electron-electron correlation must be taken into account, even at low Fe concentration. The present investigation focuses on searching for the quaternary compound where the half-metallic behavior is stable against outside influences. Overall, the results suggest that the best candidate may be found at an iron concentration of about 50%.

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Metadata

Authors
Balke, B., Fecher, G. H., Kandpal, H. C., Felser, C., Kobayashi, K., Ikenaga, E., Kim, J.-J., & Ueda, S.
Venue
Physical Review B
Published
2006-09-05
Volume
74
Issue
10
ISSN
  • 1098-0121 (ISSN-L)
  • 1550-235X
OpenAlex
W1976515283
Cited by
297
References
34
FWCI
11.53
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Properties of the quaternary half-metal-type Heusler alloyCo2Mn1−xFexSi. https://app.cochat.ai/papers/10.1103/physrevb.74.104405
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Balke, B., Fecher, G. H., Kandpal, H. C., Felser, C., Kobayashi, K., Ikenaga, E., Kim, J.-J., & Ueda, S. (2006). Properties of the quaternary half-metal-type Heusler alloyCo2Mn1−xFexSi. Physical Review B. https://doi.org/10.1103/physrevb.74.104405

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