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Cited by 599

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Optical Properties of Granular Silver and Gold Films

Cohen, R. W., Cody, G. D., Coutts, M. D., Abeles, B.·1973·Physical Review B

Abstract

Optical, electrical, and electron-microscopy studies on granular Ag-Si${\mathrm{O}}_{2}$ and Au-Si${\mathrm{O}}_{2}$ films, prepared by cosputtering the metal and the insulator, were made over the composition range 10-90% by volume Si${\mathrm{O}}_{2}$. Electron diffraction patterns indicate crystalline metals with lattice constants equal to those of the bulk metals. For films with less than 50-vol% Si${\mathrm{O}}_{2}$ the structure consists of amorphous Si${\mathrm{O}}_{2}$ inclusions in a continuous metal matrix; for films with more than 50-vol% Si${\mathrm{O}}_{2}$, separate metallic particles are dispersed in an amorphous Si${\mathrm{O}}_{2}$ continuum. Near the 50-vol% Si${\mathrm{O}}_{2}$ composition the electrical resistivity increases abruptly and the infrared transmission changes from metal-like to insulatorlike behavior. The absorption and transmission peaks in the visible, observed both in the continuous-metal as well as in the continuous-insulator regimes, are explained by a generalized Maxwell-Garnett theory. It is concluded that metal particles as small as 20 \AA{} have optical constants that do not differ significantly from those of the bulk metals.

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Metadata

Authors
Cohen, R. W., Cody, G. D., Coutts, M. D., & Abeles, B.
Venue
Physical Review B
Published
1973-10-15
Volume
8
Issue
8
Pages
3689-3701
ISSN
0556-2805 (ISSN-L)
OpenAlex
W2034588096
Cited by
599
References
14
FWCI
5.88
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Optical Properties of Granular Silver and Gold Films. https://app.cochat.ai/papers/10.1103/physrevb.8.3689
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Cohen, R. W., Cody, G. D., Coutts, M. D., & Abeles, B. (1973). Optical Properties of Granular Silver and Gold Films. Physical Review B. https://doi.org/10.1103/physrevb.8.3689

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