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Effects of Resonance Bonding on the Properties of Crystalline and Amorphous Semiconductors
Abstract
The resonance aspect of chemical bonding is extended to solids with particular emphasis on its consequences for structural and vibrational properties. It is shown, for example, that the square of the infrared effective charge is proportional to the high-frequency dielectric constant in resonance-bonded systems. The IV-VI compounds and the group-VI elements are shown to exhibit the features of such resonance bonding. The dependence of resonance bonding on long-range order is discussed with respect to differences in the properties of the amorphous and crystalline phases of these materials.
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Citations
Cited by
Resonant bonding leads to low lattice thermal conductivity
Lee, S., Esfarjani, K., Luo, T., Zhou, J., Tian, Z., & Chen, G. (2014) · Nature Communications · doi:10.1038/ncomms4525 · Cited by 679
Anharmoncity and low thermal conductivity in thermoelectrics
Chang, C., & Zhao, L.-D. (2018) · Materials Today Physics · doi:10.1016/j.mtphys.2018.02.005 · Cited by 359
The origin of incipient ferroelectricity in lead telluride
Jiang, M. P., Trigo, M., Savić, I., Fahy, S., Murray, É. D., Bray, C., Clark, J., Henighan, T., Kozina, M., Chollet, M., et al. (2016) · Nature Communications · doi:10.1038/ncomms12291 · Cited by 83
The infrared effective charge in IV-VI compounds. I. A simple one-dimensional model
Littlewood, P. B., & Heine, V (1979) · Journal of Physics C: Solid State Physics · doi:10.1088/0022-3719/12/21/011 · Cited by 48
Temperature dependence of dynamic dipole formation in PbTe
Holm, K. A. U., Roth, N., Zeuthen, C. M., Tolborg, K., Feidenhans'l, A. A., & Iversen, B. B. (2020) · Physical Review B · doi:10.1103/physrevb.102.024112 · Cited by 24
Metadata
- Authors
- Lucovsky, G., & White, R. M.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 1973-07-15
- Volume
- 8
- Issue
- 2
- Pages
- 660-667
- ISSN
- 0556-2805 (ISSN-L)
- OpenAlex
- W2023892065
- Cited by
- 270
- References
- 0
- FWCI
- 5.33
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lucovsky, G., & White, R. M. (1973). Effects of Resonance Bonding on the Properties of Crystalline and Amorphous Semiconductors. Physical Review B. https://doi.org/10.1103/physrevb.8.660
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
