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Strain tuning of optical emission energy and polarization in monolayer and bilayer MoS2
Open accessAbstract
We use micro-Raman and photoluminescence (PL) spectroscopy at 300 K to investigate the influence of uniaxial tensile strain on the vibrational and optoelectronic properties of monolayer and bilayer MoS${}_{2}$ on a flexible substrate. The initially degenerate ${E}^{\ensuremath{'}}$ monolayer Raman mode is split into a doublet as a direct consequence of the strain applied to MoS${}_{2}$ through Van der Waals coupling at the sample-substrate interface. We observe a strong shift of the direct band gap of 48 meV/(% of strain) for the monolayer and 46 meV/% for the bilayer, whose indirect gap shifts by 86 meV/%. We find a strong decrease of the PL polarization linked to optical valley initialization for both monolayer and bilayer samples, indicating that scattering to the spin-degenerate $\ensuremath{\Gamma}$ valley plays a key role.
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Cites
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
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Spin and pseudospins in layered transition metal dichalcogenides
Xu, X., Yao, W., Xiao, D., & Heinz, T. F. (2014) · Nature Physics · doi:10.1038/nphys2942 · Cited by 2,855
Photocurrent generation with two-dimensional van der Waals semiconductors
Buscema, M., Island, J. O., Groenendijk, D. J., Blanter, S. I., Steele, G. A., van der Zant, H. S. J., & Castellanos-Gomez, A. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00106d · Cited by 1,051
Enhancing Electrocatalytic Water Splitting by Strain Engineering
You, B., Tang, M. T., Tsai, C., Abild‐Pedersen, F., Zheng, X., & Li, H. (2019) · Advanced Materials · doi:10.1002/adma.201807001 · Cited by 793
Liu, G.-B., Xiao, D., Yao, Y., Xu, X., & Yao, W. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00301b · Cited by 698
Chang, C.-H., Fan, X., Lin, S.-H., & Kuo, J.-L. (2013) · Physical Review B · doi:10.1103/physrevb.88.195420 · Cited by 432
Metadata
- Authors
- Zhu, C. R., Wang, G., Liu, B. L., Marie, X., Qiao, X. F., Zhang, X., Wu, X. X., Fan, H., Tan, P. H., Amand, T., & Urbaszek, B.
- Venue
- Physical Review B
- Publisher
- American Physical Society (APS)
- Published
- 2013-09-09
- Volume
- 88
- Issue
- 12
- ISSN
- 1098-0121 (ISSN-L)
- 1550-235X
- OpenAlex
- W2044603534
- Cited by
- 465
- References
- 1
- FWCI
- 13.17
- Type
- journal article
- Language
- en
- Open access
- green
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- Zhu, C. R., Wang, G., Liu, B. L., Marie, X., Qiao, X. F., Zhang, X., Wu, X. X., Fan, H., Tan, P. H., Amand, T., & Urbaszek, B. (2013). Strain tuning of optical emission energy and polarization in monolayer and bilayer MoS2. Physical Review B. https://doi.org/10.1103/physrevb.88.121301
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