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Dynamics and thermodynamics of complex fluids. II. Illustrations of a general formalism

Öttinger, Hans Christian, Grmela, Miroslav·1997·Physical Review E

Abstract

For a number of well-known time-evolution equations for nonequilibrium systems we extract a common structure from these equations, referred to as a general equation for the nonequilibrium reversible-irreversible coupling (GENERIC). This fundamental structure is determined by four building blocks, two ``potentials'' (total energy and entropy) and two ``matrices.'' We illustrate for various examples how three of the four building blocks can be determined in a rather straightforward manner so that, within our GENERIC approach to nonequilibrium dynamics, understanding of a given nonequilibrium system is reduced to determining a single ``metric matrix,'' or friction matrix, either empirically or by more microscopic considerations. In formulating nonisothermal polymer kinetic theories, we show how the general structure provides a clear distinction between spring potentials of energetic and entropic origins in the various time-evolution equations.

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Metadata

Authors
Öttinger, H. C., & Grmela, M.
Venue
Physical Review E
Published
1997-12-01
Volume
56
Issue
6
Pages
6633-6655
ISSN
  • 1063-651X (ISSN-L)
  • 1095-3787
OpenAlex
W1983639022
Cited by
770
References
16
FWCI
14.97
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Dynamics and thermodynamics of complex fluids. II. Illustrations of a general formalism. https://app.cochat.ai/papers/10.1103/physreve.56.6633
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Öttinger, H. C., & Grmela, M. (1997). Dynamics and thermodynamics of complex fluids. II. Illustrations of a general formalism. Physical Review E. https://doi.org/10.1103/physreve.56.6633

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