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Polarizable Ions at Interfaces
Open accessAbstract
A nonperturbative theory is presented which allows us to calculate the solvation free energy of polarizable ions near water-vapor and water-oil interfaces. The theory predicts that larger halogen anions are adsorbed at the interface, while the alkali metal cations are repelled from it. The density profiles calculated theoretically are similar to those obtained using molecular dynamics simulations with polarizable force fields.
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Citations
Cited by
Bazant, M. Z., Kilic, M. S., Storey, B. D., & Ajdari, A. (2009) · Advances in Colloid and Interface Science · doi:10.1016/j.cis.2009.10.001 · Cited by 916
Understanding specific ion effects and the Hofmeister series
Gregory, K. P., Elliott, G. R., Robertson, H., Kumar, A., Wanless, E. J., Webber, G. B., Craig, V. S. J., Andersson, G. G., & Page, A. J. (2022) · Physical Chemistry Chemical Physics · doi:10.1039/d2cp00847e · Cited by 462
Accurate Determination of Ion Polarizabilities in Aqueous Solutions
Li, M., Zhuang, B., Lu, Y., Wang, Z.-G., & An, L. (2017) · The Journal of Physical Chemistry B · doi:10.1021/acs.jpcb.7b04111 · Cited by 53
Metadata
- Authors
- Levin, Y.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2009-04-08
- Volume
- 102
- Issue
- 14
- Pages
- 147803-147803
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2019882487
- Cited by
- 221
- References
- 0
- FWCI
- 12.27
- Type
- journal article
- Language
- en
- Open access
- green
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- Levin, Y. (2009). Polarizable Ions at Interfaces. Physical Review Letters. https://doi.org/10.1103/physrevlett.102.147803
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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