The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Photocatalytic Activity of BulkTiO2Anatase and Rutile Single Crystals Using Infrared Absorption Spectroscopy
Abstract
A systematic study on the photocatalytic activity of well-defined, macroscopic bulk single-crystal TiO(2) anatase and rutile samples has been carried out, which allows us to link photoreactions at surfaces of well-defined oxide semiconductors to an important bulk property with regard to photochemistry, the life time of e-h pairs generated in the bulk of the oxides by photon absorption. The anatase (101) surface shows a substantially higher activity, by an order of magnitude, for CO photo-oxidation to CO(2) than the rutile (110) surface. This surprisingly large difference in activity tracks the bulk e-h pair lifetime difference for the two TiO(2) modifications as determined by contactless transient photoconductance measurements on the corresponding bulk materials.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
Cited by
Why is anatase a better photocatalyst than rutile? - Model studies on epitaxial TiO2 films
Luttrell, T., Halpegamage, S., Tao, J., Kramer, A., Sutter, E., & Batzill, M. (2014) · Scientific Reports · doi:10.1038/srep04043 · Cited by 1,544
Cadmium sulfide-based nanomaterials for photocatalytic hydrogen production
Yuan, Y.-J., Chen, D., Yu, Z.-T., & Zou, Z.-G. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta00671g · Cited by 523
Zheng, Q., Chu, W., Zhao, C., Zhang, L., Guo, H., Wang, Y., Jiang, X., & Zhao, J. (2019) · WIREs Computational Molecular Science · doi:10.1002/wcms.1411 · Cited by 452
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Metadata
- Authors
- Xu, M., Gao, Y., Moreno, E. M., Kunst, M., Muhler, M., Wang, Y., Idriss, H., & Wöll, C.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2011-03-29
- Volume
- 106
- Issue
- 13
- Pages
- 138302-138302
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2065877072
- Cited by
- 388
- References
- 3
- FWCI
- 9.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xu, M., Gao, Y., Moreno, E. M., Kunst, M., Muhler, M., Wang, Y., Idriss, H., & Wöll, C. (2011). Photocatalytic Activity of BulkTiO2Anatase and Rutile Single Crystals Using Infrared Absorption Spectroscopy. Physical Review Letters. https://doi.org/10.1103/physrevlett.106.138302
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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