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Near-Unity Quantum Yields of Biexciton Emission fromCdSe/CdSNanocrystals Measured Using Single-Particle Spectroscopy
Abstract
Biexciton photoluminescence (PL) quantum yields (Q(2X)) of individual CdSe/CdS core-shell nanocrystal quantum dots with various shell thicknesses are derived from independent PL saturation and two-photon correlation measurements. We observe a near-unity Q(2X) for some nanocrystals with an ultrathick 19-monolayer shell. High Q(2X)'s are, however, not universal and vary widely among nominally identical nanocrystals indicating a significant dependence of Q(2X) upon subtle structural differences. Interestingly, our measurements indicate that high Q(2X)'s are not required to achieve complete suppression of PL intensity fluctuations in individual nanocrystals.
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Cites
A semiconductor source of triggered entangled photon pairs
Stevenson, R. M., Young, R. J., Atkinson, P., Cooper, K., Ritchie, D. A., & Shields, A. J. (2006) · Nature · doi:10.1038/nature04446 · Cited by 914
Cited by
Bae, W. K., Padilha, L. A., Park, Y.-S., McDaniel, H., Robel, I., Pietryga, J. M., & Klimov, V. I. (2013) · ACS Nano · doi:10.1021/nn4002825 · Cited by 508
Self-citationElectronic Impurity Doping in CdSe Nanocrystals
Sahu, A., Kang, M. S., Kompch, A., Notthoff, C., Wills, A. W., Deng, D., Winterer, M., Frisbie, C. D., & Norris, D. J. (2012) · Nano Letters · doi:10.1021/nl300880g · Cited by 375
Metadata
- Authors
- Park, Y.-S., Malko, A. V., Vela, J., Chen, Y., Ghosh, Y., García-Santamaría, F., Hollingsworth, J. A., Klimov, V. I., & Htoon, H.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2011-05-03
- Volume
- 106
- Issue
- 18
- Pages
- 187401-187401
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2079211552
- Cited by
- 219
- References
- 1
- FWCI
- 9.76
- Type
- journal article
- Language
- en
- Open access
- closed
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- Park, Y.-S., Malko, A. V., Vela, J., Chen, Y., Ghosh, Y., García-Santamaría, F., Hollingsworth, J. A., Klimov, V. I., & Htoon, H. (2011). Near-Unity Quantum Yields of Biexciton Emission fromCdSe/CdSNanocrystals Measured Using Single-Particle Spectroscopy. Physical Review Letters. https://doi.org/10.1103/physrevlett.106.187401
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