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Near-Unity Quantum Yields of Biexciton Emission fromCdSe/CdSNanocrystals Measured Using Single-Particle Spectroscopy

Park, Y.-S., Malko, A. V., Vela, J., Chen, Y., Ghosh, Y., García-Santamaría, F., Hollingsworth, J. A., Klimov, V. I., Htoon, H.·2011·Physical Review Letters

Abstract

Biexciton photoluminescence (PL) quantum yields (Q(2X)) of individual CdSe/CdS core-shell nanocrystal quantum dots with various shell thicknesses are derived from independent PL saturation and two-photon correlation measurements. We observe a near-unity Q(2X) for some nanocrystals with an ultrathick 19-monolayer shell. High Q(2X)'s are, however, not universal and vary widely among nominally identical nanocrystals indicating a significant dependence of Q(2X) upon subtle structural differences. Interestingly, our measurements indicate that high Q(2X)'s are not required to achieve complete suppression of PL intensity fluctuations in individual nanocrystals.

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Metadata

Authors
Park, Y.-S., Malko, A. V., Vela, J., Chen, Y., Ghosh, Y., García-Santamaría, F., Hollingsworth, J. A., Klimov, V. I., & Htoon, H.
Venue
Physical Review Letters
Published
2011-05-03
Volume
106
Issue
18
Pages
187401-187401
ISSN
  • 0031-9007 (ISSN-L)
  • 1079-7114
OpenAlex
W2079211552
Cited by
219
References
1
FWCI
9.76
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Near-Unity Quantum Yields of Biexciton Emission fromCdSe/CdSNanocrystals Measured Using Single-Particle Spectroscopy. https://app.cochat.ai/papers/10.1103/physrevlett.106.187401
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Park, Y.-S., Malko, A. V., Vela, J., Chen, Y., Ghosh, Y., García-Santamaría, F., Hollingsworth, J. A., Klimov, V. I., & Htoon, H. (2011). Near-Unity Quantum Yields of Biexciton Emission fromCdSe/CdSNanocrystals Measured Using Single-Particle Spectroscopy. Physical Review Letters. https://doi.org/10.1103/physrevlett.106.187401

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