The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Hydrogenation and Disorder in Engineered BlackTiO2
Abstract
A new form of TiO2 which is black in color has been shown to exhibit high efficiency for photocatalytic reactions under solar radiation [X. Chen, L. Liu, P. Y. Yu, and S. S. Mao, Science 331, 746 (2011)]. However, the mechanism behind this disorder-engineering process is not fully understood. In this Letter, based on density functional theory, we describe the role of hydrogen in producing lattice disorder in the anatase nanocrystals. We clarify further that the highly localized nature of the midgap states results in spatial separation of photoexcited electrons and holes in black TiO2, and that accounts for its high photocatalytic efficiency.
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Citations
Cites
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
Semiconductor-based Photocatalytic Hydrogen Generation
Chen, X., Shen, S., Guo, L., & Mao, S. S. (2010) · Chemical Reviews · doi:10.1021/cr1001645 · Cited by 7,876
Self-citation
Cited by
Photocatalysis with Reduced TiO2: From Black TiO2 to Cocatalyst-Free Hydrogen Production
Naldoni, A., Altomare, M., Zoppellaro, G., Liu, N., Kment, Š., Zbořil, R., & Schmuki, P. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04068 · Cited by 770
Hydrogenated TiO2 Nanocrystals: A Novel Microwave Absorbing Material
Xia, T., Zhang, C., Oyler, N. A., & Chen, X. (2013) · Advanced Materials · doi:10.1002/adma.201303088 · Cited by 559
Self-citationEnergy transfer in plasmonic photocatalytic composites
Ma, X.-C., Dai, Y., Yu, L., & Huang, B.-B. (2016) · Light: Science & Applications · doi:10.1038/lsa.2016.17 · Cited by 553
Cadmium sulfide-based nanomaterials for photocatalytic hydrogen production
Yuan, Y.-J., Chen, D., Yu, Z.-T., & Zou, Z.-G. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta00671g · Cited by 523
Li, J., Zhang, M., Guan, Z., Li, Q., He, C., & Yang, J. (2017) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2017.01.025 · Cited by 503
Metadata
- Authors
- Liu, L., Yu, P. Y., Chen, X., Mao, S. S., & Shen, D. Z.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2013-08-08
- Volume
- 111
- Issue
- 6
- Pages
- 065505-065505
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2320344804
- Cited by
- 222
- References
- 3
- FWCI
- 8.30
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, L., Yu, P. Y., Chen, X., Mao, S. S., & Shen, D. Z. (2013). Hydrogenation and Disorder in Engineered BlackTiO2. Physical Review Letters. https://doi.org/10.1103/physrevlett.111.065505
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