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Observation of Two-Dimensional Phases Associated with Defect States on the Surface of TiO2
Abstract
Surface electronic states associated with defects produced by Ar-ion bombardment of Ti${\mathrm{O}}_{2}$ crystals have been studied by ultraviolet-photoemission, electron-energy-loss, and Auger spectroscopy and low-energy-electron diffraction. Evidence is given for three distinct phases dependent upon the extrinsic surface-defect concentration. Phase I contains isolated surface states 0.7 eV below the conduction band, phase II is associated with the creation of ${\mathrm{Ti}}^{3+}$ pairs, and phase III consists of a surface layer of ordered ${\mathrm{Ti}}_{2}$${\mathrm{O}}_{3}$.
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Citations
Cited by
The surface science of titanium dioxide
Diebold, U. (2003) · Surface Science Reports · doi:10.1016/s0167-5729(02)00100-0 · Cited by 7,944
Tuning defects in oxides at room temperature by lithium reduction
Ou, G., Xu, Y., Wen, B., Lin, R., Ge, B., Tang, Y., Liang, Y., Yang, C., Huang, K., Zu, D., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-03765-0 · Cited by 722
Metal–Support Interaction: Group VIII Metals and Reducible Oxides
(1989) · Advances in Catalysis · doi:10.1016/s0360-0564(08)60018-8 · Cited by 667
Wendt, S., Schaub, R., Matthiesen, J., Vestergaard, E. K., Wahlström, E., Rasmussen, M. D., Thostrup, P., Molina, L. M., Lægsgaard, E., Stensgaard, I., et al. (2005) · Surface Science · doi:10.1016/j.susc.2005.08.041 · Cited by 600
Finazzi, E., Di Valentin, C., Pacchioni, G., & Selloni, A. (2008) · The Journal of Chemical Physics · doi:10.1063/1.2996362 · Cited by 543
Metadata
- Authors
- Henrich, V. E., Dresselhaus, G., & Zeiger, H. J.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1976-05-31
- Volume
- 36
- Issue
- 22
- Pages
- 1335-1339
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W283640366
- Cited by
- 506
- References
- 0
- FWCI
- 7.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Henrich, V. E., Dresselhaus, G., & Zeiger, H. J. (1976). Observation of Two-Dimensional Phases Associated with Defect States on the Surface of TiO2. Physical Review Letters. https://doi.org/10.1103/physrevlett.36.1335
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