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Core-Level Binding Energy and Density of States from the Surface Atoms of Gold
Abstract
X-ray photoemission spectra of $4f$ and valence electrons in surface atoms of gold have been obtained. The surface-atom $4f$ level is shifted 0.40\ifmmode\pm\else\textpm\fi{}0.01 eV to lower binding energy relative to the bulk value. The surface density of states is narrowed by (7.6 \ifmmode\pm\else\textpm\fi{} 1.1)% and its center of gravity is shifted to lower binding energy by 0.51\ifmmode\pm\else\textpm\fi{}0.08 eV. A model is proposed to account for the core-level shift in terms of the modified surface density of states.
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Citations
Cited by
Electronic structure of supported small metal clusters
Mason, M. G. (1983) · Physical Review B · doi:10.1103/physrevb.27.748 · Cited by 936
A new approach on the Cu UPD on Ag surfaces
Thiel, K.-O., Hintze, M., Vollmer, A., & Donner, C. (2008) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2008.03.001 · Cited by 15
Metadata
- Authors
- Citrin, P. H., Wertheim, G. K., & Baer, Y.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1978-11-13
- Volume
- 41
- Issue
- 20
- Pages
- 1425-1428
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W1967061794
- Cited by
- 427
- References
- 0
- FWCI
- 14.15
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Core-Level Binding Energy and Density of States from the Surface Atoms of Gold. https://app.cochat.ai/papers/10.1103/physrevlett.41.1425
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- Citrin, P. H., Wertheim, G. K., & Baer, Y. (1978). Core-Level Binding Energy and Density of States from the Surface Atoms of Gold. Physical Review Letters. https://doi.org/10.1103/physrevlett.41.1425
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.