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Structural Origin of Optical Bowing in Semiconductor Alloys
Abstract
The principle of conservation and transferability of chemical bonds explains the recent discovery by extended x-ray-absorption fine-structure measurements of two unequal anion-cation bond lengths ${R}_{\mathrm{AC}}$ and ${R}_{\mathrm{BC}}$ in ${A}_{x}{B}_{1\ensuremath{-}x}C$ zinc-blende semiconductor alloys despite the close adherence of the lattice constant to the average value (V\'egard rule). This bond alternation, manifested as a structural distortion to a local chalcopyrite coordination around the anions, explains also most of the observed optical bowing in semiconductor alloys.
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Citations
Cited by
Electronic structure of ZnS, ZnSe, ZnTe, and their pseudobinary alloys
Bernard, J. E., & Zunger, A. (1987) · Physical Review B · doi:10.1103/physrevb.36.3199 · Cited by 440
Self-citationBond lengths around isovalent impurities and in semiconductor solid solutions
Martins, J. L., & Zunger, A. (1984) · Physical Review B · doi:10.1103/physrevb.30.6217 · Cited by 435
Self-citationAtomic structure and ordering in semiconductor alloys
Srivastava, G. P., Martins, J. L., & Zunger, A. (1985) · Physical Review B · doi:10.1103/physrevb.31.2561 · Cited by 368
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Metadata
- Authors
- Zunger, A., & Jaffe, J. E.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1983-08-22
- Volume
- 51
- Issue
- 8
- Pages
- 662-665
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W2010789626
- Cited by
- 209
- References
- 0
- FWCI
- 8.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zunger, A., & Jaffe, J. E. (1983). Structural Origin of Optical Bowing in Semiconductor Alloys. Physical Review Letters. https://doi.org/10.1103/physrevlett.51.662
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