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Photofragmentation of Mass-ResolvedSi2−12+Clusters
Abstract
The photofragmentation spectra of ${{\mathrm{Si}}_{n}}^{+}$ for $n=2 \mathrm{to} 12$ have been obtained in an apparatus that produces, isolates, and fragments ionic clusters on a mass-resolved basis. The most prominent species are found to be ${\mathrm{Si}}_{6}^{+}$ and ${\mathrm{Si}}_{10}^{+}$. The fragmentation data are shown to be consistent with a microcrystal model of cluster geometry for ${{\mathrm{Si}}_{n}}^{+}$.
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Citations
Cited by
Super Atomic Clusters: Design Rules and Potential for Building Blocks of Materials
Jena, P., & Sun, Q. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00524 · Cited by 673
Structure, stability, and fragmentation of small carbon clusters
Raghavachari, K., & Binkley, J. S. (1987) · The Journal of Chemical Physics · doi:10.1063/1.453145 · Cited by 638
Bonding and stabilities of small silicon clusters: A theoretical study of Si7–Si1
Raghavachari, K., & Rohlfing, C. M. (1988) · The Journal of Chemical Physics · doi:10.1063/1.455065 · Cited by 465
Electronic Shell Structure and Metal Clusters
de Heer, W. A., Knight, W. D., Chou, M. Y., & Cohen, M. L. (1987) · Solid State Physics · doi:10.1016/s0081-1947(08)60691-8 · Cited by 438
Structure and bonding in small silicon clusters
Raghavachari, K., & Logovinsky, V. (1985) · Physical Review Letters · doi:10.1103/physrevlett.55.2853 · Cited by 405
Metadata
- Authors
- Bloomfield, L. A., Freeman, R. R., & Brown, W. L.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1985-05-20
- Volume
- 54
- Issue
- 20
- Pages
- 2246-2249
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W2325331833
- Cited by
- 407
- References
- 0
- FWCI
- 58.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bloomfield, L. A., Freeman, R. R., & Brown, W. L. (1985). Photofragmentation of Mass-ResolvedSi2−12+Clusters. Physical Review Letters. https://doi.org/10.1103/physrevlett.54.2246
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