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Free-energy model for the inhomogeneous hard-sphere fluid mixture and density-functional theory of freezing
Abstract
A free-energy density functional for the inhomogeneous hard-sphere fluid mixture is derived from general basic considerations and yields explicit analytic expressions for the high-order direct correlation functions of the uniform fluid. It provides the first unified derivation of the most comprehensive available analytic description of the hard-sphere thermodynamics and pair structure as given by the scaled-particle and Percus-Yevick theories. The infinite-order expansion around a uniform reference state does not lead, however, to a stable solid, thus questioning the convergence of the density-functional theory of freezing.
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Cited by
A quasi-universal scaling law for atomic transport in simple fluids
Rosenfeld, Y. (1999) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/11/28/303 · Cited by 494
Self-citationMicroscopic Simulations of Electrochemical Double-Layer Capacitors
Jeanmairet, G., Rotenberg, B., & Salanne, M. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00925 · Cited by 303
Metadata
- Authors
- Rosenfeld, Y.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1989-08-28
- Volume
- 63
- Issue
- 9
- Pages
- 980-983
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W1972270832
- Cited by
- 1,614
- References
- 0
- FWCI
- 10.83
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Free-energy model for the inhomogeneous hard-sphere fluid mixture and density-functional theory of freezing. https://app.cochat.ai/papers/10.1103/physrevlett.63.980
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- Rosenfeld, Y. (1989). Free-energy model for the inhomogeneous hard-sphere fluid mixture and density-functional theory of freezing. Physical Review Letters. https://doi.org/10.1103/physrevlett.63.980
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
