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Electronic structure of solidC60: Experiment and theory
Abstract
Synchrotron-radiation and x-ray photoemission studies of the valence states of condensed phase-pure ${\mathrm{C}}_{60}$ showed seventeen distinct molecular fetaures extending \ensuremath{\sim}23 eV below the highest occupied molecular states with intensity variations due to matrix-element effects involving both cluster and free-electron-like final states. Pseudopotential calculations established the orign of these features, and comparison with experiment was excellent. The sharp C 1s main line indicated a single species, and the nine satellite structures were due to shakeup and plasmon features. The 1.9-eV feature reflected transitions to the lowest unoccupied molecular level of the excited state.
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Cited by
Moriarty, P. (2001) · Reports on Progress in Physics · doi:10.1088/0034-4885/64/3/201 · Cited by 785
Structure of single-phase superconducting K3C60
Stephens, P. W., Mihaly, L., Lee, P. L., Whetten, R. L., Huang, S.-M., Kaner, R., Deiderich, F., & Holczer, K. (1991) · Nature · doi:10.1038/351632a0 · Cited by 734
Isolation and properties of small-bandgap fullerenes
Diener, M. D., & Alford, J. M. (1998) · Nature · doi:10.1038/31435 · Cited by 332
Metadata
- Authors
- Weaver, J. H., Martins, J. L., Komeda, T., Chen, Y., Ohno, T. R., Kroll, G. H., Troullier, N., Haufler, R. E., & Smalley, R. E.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1991-04-01
- Volume
- 66
- Issue
- 13
- Pages
- 1741-1744
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W2057747805
- Cited by
- 592
- References
- 0
- FWCI
- 99.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Electronic structure of solidC60: Experiment and theory. https://app.cochat.ai/papers/10.1103/physrevlett.66.1741
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- Weaver, J. H., Martins, J. L., Komeda, T., Chen, Y., Ohno, T. R., Kroll, G. H., Troullier, N., Haufler, R. E., & Smalley, R. E. (1991). Electronic structure of solidC60: Experiment and theory. Physical Review Letters. https://doi.org/10.1103/physrevlett.66.1741
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