The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Nature of nonexponential loss of correlation above the glass transition investigated by multidimensional NMR
Abstract
A two-dimensional (2D) and a novel ``reduced four-dimensional (4D)'' exchange NMR experiment are applied to investigate slow dynamics in poly(vinyl acetate) 20 K above its ${\mathit{T}}_{\mathit{g}}$. The 2D $^{13}\mathrm{C}$ NMR spectra indicate a diffusive process with strongly nonexponential loss of correlation. In the ``reduced 4D'' experiment, the underlying distribution of correlation times is found to be heterogeneous on the time scale of the average correlation time, becoming homogeneous, however, at later times due to fluctuations which are 2 orders of magnitude slower.
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Williams, M. L., Landel, R. F., & Ferry, J. D. (1955) · Journal of the American Chemical Society · doi:10.1021/ja01619a008 · Cited by 8,083
Cited by
Formation of Glasses from Liquids and Biopolymers
Angell, C. A. (1995) · Science · doi:10.1126/science.267.5206.1924 · Cited by 4,799
The role of local structure in dynamical arrest
Royall, C. P., & Williams, S. R. (2015) · Physics Reports · doi:10.1016/j.physrep.2014.11.004 · Cited by 473
Tanaka, H. (2012) · The European Physical Journal E · doi:10.1140/epje/i2012-12113-y · Cited by 347
Metadata
- Authors
- Schmidt-Rohr, K., & Spiess, H. W.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1991-06-10
- Volume
- 66
- Issue
- 23
- Pages
- 3020-3023
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W2034875509
- Cited by
- 645
- References
- 1
- FWCI
- 18.41
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Nature of nonexponential loss of correlation above the glass transition investigated by multidimensional NMR. https://app.cochat.ai/papers/10.1103/physrevlett.66.3020
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- Schmidt-Rohr, K., & Spiess, H. W. (1991). Nature of nonexponential loss of correlation above the glass transition investigated by multidimensional NMR. Physical Review Letters. https://doi.org/10.1103/physrevlett.66.3020
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