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Vibrational spectroscopy of water at the vapor/water interface
Abstract
Using infrared-visible sum-frequency generation we have obtained the OH stretch vibrational spectra of water at the vapor/water interface. From the spectra, we deduce that more than 20% of the surface water molecules have one free OH projecting into the vapor. The spectrum is weakly temperature dependent from 10 to 80 \ifmmode^\circ\else\textdegree\fi{}C. A monolayer of fatty alcohol on water surface terminates the free OH groups and induces an icelike structure in the spectrum.
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Citations
Cited by
Infrared spectroscopy of proteins
Barth, A. (2007) · Biochimica et Biophysica Acta (BBA) - Bioenergetics · doi:10.1016/j.bbabio.2007.06.004 · Cited by 5,129
“The symmetric and antisymmetric stretching vibrations of non-hydrogen bonded water absorb between 3630 and 3760 cm − 1 [274,277,292 – 296], whereas bonded OH groups absorb between 3600 and 2900 cm − 1 depending on the strength and pattern of hydrogen bonding [274,277,295].”
BackgroundStructure and reactivity of water at biomaterial surfaces
Vogler, E. A. (1998) · Advances in Colloid and Interface Science · doi:10.1016/s0001-8686(97)00040-7 · Cited by 1,640
Interface-Assisted Synthesis of 2D Materials: Trend and Challenges
Dong, R., Zhang, T., & Feng, X. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00056 · Cited by 710
Hydrogen bonding at the water surface revealed by isotopic dilution spectroscopy
Stiopkin, I. V., Weeraman, C., Pieniazek, P. A., Shalhout, F. Y., Skinner, J. L., & Benderskii, A. V. (2011) · Nature · doi:10.1038/nature10173 · Cited by 462
Molecular reactions at aqueous interfaces
Ruiz-Lopez, M. F., Francisco, J. S., Martins-Costa, M. T. C., & Anglada, J. M. (2020) · Nature Reviews Chemistry · doi:10.1038/s41570-020-0203-2 · Cited by 411
Metadata
- Authors
- Du, Q., Superfine, R., Freysz, E., & Shen, Y. R.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1993-04-12
- Volume
- 70
- Issue
- 15
- Pages
- 2313-2316
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W2000827899
- Cited by
- 1,035
- References
- 0
- FWCI
- 9.82
- Type
- journal article
- Language
- en
- Open access
- closed
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- Du, Q., Superfine, R., Freysz, E., & Shen, Y. R. (1993). Vibrational spectroscopy of water at the vapor/water interface. Physical Review Letters. https://doi.org/10.1103/physrevlett.70.2313
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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