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Structural Properties of a Carbon-Nanotube Crystal
Abstract
Carbon nanotubes of uniform size may soon be available in macroscopic quantities. Here we examine the ordered condensed phase of these tubes. As the tube diameter varies, the structural properties show a clear transition between two regimes with qualitatively different behavior. Tubes 10 \AA{} and less in diameter behave as rigid cylinders. For diameters over 25 \AA{}, the tubes flatten against each other under the van der Waals attraction, forming a honeycomb structure. This structure exhibits an anomalous rigidity, which does not decrease as expected with increasing tube diameter. Based on reported tube sizes, both regimes should be experimentally accessible.
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Cited by
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Yu, M.-F., Files, B. S., Arepalli, S., & Ruoff, R. S. (2000) · Physical Review Letters · doi:10.1103/physrevlett.84.5552 · Cited by 2,696
Self-citationNanomechanics of Carbon Tubes: Instabilities beyond Linear Response
Yakobson, B. I., Brabec, C. J., & Bernholc, J. (1996) · Physical Review Letters · doi:10.1103/physrevlett.76.2511 · Cited by 2,642
Structural flexibility of carbon nanotubes
Iijima, S., Brabec, C., Maiti, A., & Bernholc, J. (1996) · The Journal of Chemical Physics · doi:10.1063/1.470966 · Cited by 1,250
The revolutionary creation of new advanced materials—carbon nanotube composites
Lau, A. K.-T., & Hui, D. (2002) · Composites Part B: Engineering · doi:10.1016/s1359-8368(02)00012-4 · Cited by 1,020
Energy Gaps in "Metallic" Single-Walled Carbon Nanotubes
Ouyang, M., Huang, J.-L., Cheung, C. L., & Lieber, C. M. (2001) · Science · doi:10.1126/science.1058853 · Cited by 730
Metadata
- Authors
- Tersoff, J., & Ruoff, R. S.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1994-08-01
- Volume
- 73
- Issue
- 5
- Pages
- 676-679
- ISSN
- 0031-9007 (ISSN-L)
- OpenAlex
- W1969589481
- Cited by
- 472
- References
- 0
- FWCI
- 10.41
- Type
- journal article
- Language
- en
- Open access
- closed
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