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Dielectric Dispersion Measurements of CdSe Nanocrystal Colloids: Observation of a Permanent Dipole Moment
Abstract
We measure the dielectric dispersion of CdSe nanocrystal colloids and show the existence of large dipole moments of 25 and 47 debye for 34 and 46 \AA{} diameter nanocrystals, respectively. The magnitude is consistent with the expected spontaneous polarization of the bulk wurtzite CdSe lattice and implies a potential drop of $\ensuremath{\approx}0.25\mathrm{V}$ across the nanocrystal. This effect, which is intrinsic to the wurtzite structure but has been largely overlooked, should be incorporated in the description of the quantum confined electronic states.
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Citations
Cites
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
Cited by
Synthesis and Characterization of Monodisperse Nanocrystals and Close-Packed Nanocrystal Assemblies
Murray, C. B., Kagan, C. R., & Bawendi, M. G. (2000) · Annual Review of Materials Science · doi:10.1146/annurev.matsci.30.1.545 · Cited by 4,353
Bright UV-Blue Luminescent Colloidal ZnSe Nanocrystals
Hines, M. A., & Guyot-Sionnest, P. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp9810217 · Cited by 554
Self-citationXu, X., Zhuang, J., & Wang, X. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8040527 · Cited by 408
Intraband relaxation in CdSe quantum dots
Guyot-Sionnest, P., Shim, M., Matranga, C., & Hines, M. (1999) · Physical Review B · doi:10.1103/physrevb.60.r2181 · Cited by 393
Self-citationKambhampati, P. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp2058673 · Cited by 391
Metadata
- Authors
- Blanton, S. A., Leheny, R. L., Hines, M. A., & Guyot-Sionnest, P.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 1997-08-04
- Volume
- 79
- Issue
- 5
- Pages
- 865-868
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2047688126
- Cited by
- 172
- References
- 1
- FWCI
- 5.88
- Type
- journal article
- Language
- en
- Open access
- closed
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- Blanton, S. A., Leheny, R. L., Hines, M. A., & Guyot-Sionnest, P. (1997). Dielectric Dispersion Measurements of CdSe Nanocrystal Colloids: Observation of a Permanent Dipole Moment. Physical Review Letters. https://doi.org/10.1103/physrevlett.79.865
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