The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Direct Measurement of Interfacial Curvature Distributions in a Bicontinuous Block Copolymer Morphology
Abstract
Self-consistent field theory predicts that the complex phase behavior of block copolymers does not originate solely from the interface seeking constant mean curvature as once thought, but instead reflects competing minimization of interfacial tension and packing frustration. To test this prediction, we directly measure interfacial curvature distributions from a 3D image reconstruction of the bicontinuous gyroid morphology. Results obtained here reveal that the gyroid interface is not constant mean curvature and confirm the importance of packing frustration in the stabilization of such complex nanostructures.
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Citations
Cites
Origins of complex self-assembly in block copolymers
Matsen, M. W., & Bates, F. S. (1996) · Macromolecules · doi:10.1021/ma960744q · Cited by 578
Cited by
The standard Gaussian model for block copolymer melts
Matsen, M. W. (2002) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/14/2/201 · Cited by 657
Thermoplastic elastomers: fundamentals and applications
Spontak, R. J., & Patel, N. P. (2000) · Current Opinion in Colloid & Interface Science · doi:10.1016/s1359-0294(00)00070-4 · Cited by 408
Self-citationTriply Periodic Bicontinuous Cubic Microdomain Morphologies by Symmetries
Wohlgemuth, M., Yufa, N., Hoffman, J., & Thomas, E. L. (2001) · Macromolecules · doi:10.1021/ma0019499 · Cited by 295
Metadata
- Authors
- Jinnai, H., Nishikawa, Y., Spontak, R. J., Smith, S. D., Agard, D. A., & Hashimoto, T.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2000-01-17
- Volume
- 84
- Issue
- 3
- Pages
- 518-521
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2034486452
- Cited by
- 194
- References
- 1
- FWCI
- 6.23
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jinnai, H., Nishikawa, Y., Spontak, R. J., Smith, S. D., Agard, D. A., & Hashimoto, T. (2000). Direct Measurement of Interfacial Curvature Distributions in a Bicontinuous Block Copolymer Morphology. Physical Review Letters. https://doi.org/10.1103/physrevlett.84.518
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