The DOI matches its Crossref record; 19 of the 19 references it cites were found in a registry or an index.
Nanoscopic-Confinement Effects on Local Dynamics
Abstract
The segmental dynamics of 1.5-2.0 nm polymer films confined between parallel solid surfaces is investigated with dielectric spectroscopy in polymer/silicate intercalated nanocomposites. The confinement effect is evident by the observation of a mode, much faster than the bulk-polymer alpha relaxation and exhibiting much weaker temperature dependence. This is discussed in relation to either the interlayer spacing restricting the cooperative volume of the alpha relaxation or to the dominance of the more mobile interphase regions as predicted by simulations; the data qualitatively support the former.
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Citations
Cites
Polymer Layered Silicate Nanocomposites
Giannelis, E. P. (1996) · Advanced Materials · doi:10.1002/adma.19960080104 · Cited by 3,479
Self-citationTheory of Electric Polarization
Böttcher, C. J. F., van Belle, O. C., Bordewijk, P., Rip, A., & Yue, D. D. (1974) · Journal of The Electrochemical Society · doi:10.1149/1.2402382 · Cited by 3,352
Size-Dependent Depression of the Glass Transition Temperature in Polymer Films
Keddie, J. L., Jones, R. A. L., & Cory, R. A. (1994) · Europhysics Letters (EPL) · doi:10.1209/0295-5075/27/1/011 · Cited by 1,808
Polymer-Silicate Nanocomposites: Model Systems for Confined Polymers and Polymer Brushes
Giannelis, E. P., Krishnamoorti, R., & Manias, E. (1999) · Advances in Polymer Science · doi:10.1007/3-540-69711-x_3 · Cited by 1,129
Self-citationEffect of Free Surfaces on the Glass Transition Temperature of Thin Polymer Films
Forrest, J. A., Dalnoki-Veress, K., Stevens, J. R., & Dutcher, J. R. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.2002 · Cited by 1,106
Interface and surface effects on the glass-transition temperature in thin polymer films
Keddie, J. L., Jones, R. A. L., & Cory, R. A. (1994) · Faraday Discussions · doi:10.1039/fd9949800219 · Cited by 1,013
Vaia, R. A., & Giannelis, E. P. (1997) · Macromolecules · doi:10.1021/ma9603488 · Cited by 1,007
Self-citationInterlayer Structure and Molecular Environment of Alkylammonium Layered Silicates
Vaia, R. A., Teukolsky, R. K., & Giannelis, E. P. (1994) · Chemistry of Materials · doi:10.1021/cm00043a025 · Cited by 902
Self-citationStructure and Dynamics of Polymer-Layered Silicate Nanocomposites
Krishnamoorti, R., Vaia, R. A., & Giannelis, E. P. (1996) · Chemistry of Materials · doi:10.1021/cm960127g · Cited by 901
Self-citationLattice Model of Polymer Melt Intercalation in Organically-Modified Layered Silicates
Vaia, R. A., & Giannelis, E. P. (1997) · Macromolecules · doi:10.1021/ma9514333 · Cited by 827
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Cited by
Polymer nanotechnology: Nanocomposites
Paul, D. R., & Robeson, L. M. (2008) · Polymer · doi:10.1016/j.polymer.2008.04.017 · Cited by 3,317
Modeling properties of nylon 6/clay nanocomposites using composite theories
Fornes, T. D., & Paul, D. R. (2003) · Polymer · doi:10.1016/s0032-3861(03)00471-3 · Cited by 990
Molecular dynamics simulation of a polymer melt with a nanoscopic particle
Starr, F. W., Schrøder, T. B., & Glotzer, S. C. (2002) · Macromolecules · doi:10.1021/ma010626p · Cited by 511
Krishnamoorti, R., & Vaia, R. A. (2007) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.21319 · Cited by 322
Glass transition and chain mobility in thin polymer films
Roth, C. B., & Dutcher, J. R. (2005) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2004.03.003 · Cited by 314
Metadata
- Authors
- Anastasiadis, S. H., Karatasos, K., Vlachos, G., Manias, E., & Giannelis, E. P.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2000-01-31
- Volume
- 84
- Issue
- 5
- Pages
- 915-918
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2017771574
- Cited by
- 291
- References
- 19
- FWCI
- 15.29
- Type
- journal article
- Language
- en
- Open access
- closed
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- Anastasiadis, S. H., Karatasos, K., Vlachos, G., Manias, E., & Giannelis, E. P. (2000). Nanoscopic-Confinement Effects on Local Dynamics. Physical Review Letters. https://doi.org/10.1103/physrevlett.84.915
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