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X-Ray Emission Spectroscopy of Hydrogen Bonding and Electronic Structure of Liquid Water

Guo, J.-H., Luo, Y., Augustsson, A., Rubensson, J.-E., Såthe, C., Ågren, H., Siegbahn, H., Nordgren, J.·2002·Physical Review Letters

Abstract

We use x-ray emission spectroscopy to examine the influence of the intermolecular interaction on the local electronic structure of liquid water. By comparing x-ray emission spectra of the water molecule and liquid water, we find a strong involvement of the a(1)-symmetry valence-orbital in the hydrogen bonding. The local electronic structure of water molecules, where one hydrogen bond is broken at the hydrogen site, is separately determined. Our results provide an illustration of the important potential of x-ray emission spectroscopy for elucidating basic features of liquids.

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Metadata

Authors
Guo, J.-H., Luo, Y., Augustsson, A., Rubensson, J.-E., Såthe, C., Ågren, H., Siegbahn, H., & Nordgren, J.
Venue
Physical Review Letters
Published
2002-09-09
Volume
89
Issue
13
Pages
137402-137402
ISSN
  • 0031-9007 (ISSN-L)
  • 1079-7114
OpenAlex
W2023223453
Cited by
268
References
1
FWCI
12.02
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: X-Ray Emission Spectroscopy of Hydrogen Bonding and Electronic Structure of Liquid Water. https://app.cochat.ai/papers/10.1103/physrevlett.89.137402
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Guo, J.-H., Luo, Y., Augustsson, A., Rubensson, J.-E., Såthe, C., Ågren, H., Siegbahn, H., & Nordgren, J. (2002). X-Ray Emission Spectroscopy of Hydrogen Bonding and Electronic Structure of Liquid Water. Physical Review Letters. https://doi.org/10.1103/physrevlett.89.137402

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