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Hole- and Electron-Vibrational Couplings in Oligoacene Crystals: Intramolecular Contributions
Abstract
The hole-vibrational coupling is reported for anthracene, tetracene, and pentacene on the basis of a joint experimental and theoretical study of ionization spectra using high-resolution gas-phase photoelectron spectroscopy and first-principles correlated quantum-mechanical calculations. The hole-vibrational coupling is found to be significantly smaller than the electron-vibrational coupling in the case of these oligomers; however, both quantities are predicted to converge to the same value when increasing the chain length.
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Cites
Electron transfer reactions in chemistry. Theory and experiment
Marcus, R. A. (1993) · Reviews of Modern Physics · doi:10.1103/revmodphys.65.599 · Cited by 3,667
Cited by
Role of Molecular Order and Solid-State Structure in Organic Field-Effect Transistors
Mas-Torrent, M., & Rovira, C. (2011) · Chemical Reviews · doi:10.1021/cr100142w · Cited by 560
Ueno, N., & Kera, S. (2008) · Progress in Surface Science · doi:10.1016/j.progsurf.2008.10.002 · Cited by 269
Ambipolar Transport in Organic Conjugated Materials
Cornil, J., Brédas, J. ‐., Zaumseil, J., & Sirringhaus, H. (2007) · Advanced Materials · doi:10.1002/adma.200602922 · Cited by 261
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Metadata
- Authors
- Coropceanu, V., Malagoli, M., da Silva Filho, D. A., Gruhn, N. E., Bill, T. G., & Brédas, J. L.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2002-12-20
- Volume
- 89
- Issue
- 27
- Pages
- 275503-275503
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2067710498
- Cited by
- 399
- References
- 1
- FWCI
- 17.18
- Type
- journal article
- Language
- en
- Open access
- closed
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- Coropceanu, V., Malagoli, M., da Silva Filho, D. A., Gruhn, N. E., Bill, T. G., & Brédas, J. L. (2002). Hole- and Electron-Vibrational Couplings in Oligoacene Crystals: Intramolecular Contributions. Physical Review Letters. https://doi.org/10.1103/physrevlett.89.275503
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