The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Bonding of Gold Nanoclusters to Oxygen Vacancies on RutileTiO2(110)
Open accessAbstract
Through an interplay between scanning tunneling microscopy (STM) and density functional theory (DFT) calculations, we show that bridging oxygen vacancies are the active nucleation sites for Au clusters on the rutile TiO2(110) surface. We find that a direct correlation exists between a decrease in density of vacancies and the amount of Au deposited. From the DFT calculations we find that the oxygen vacancy is indeed the strongest Au binding site. We show both experimentally and theoretically that a single oxygen vacancy can bind 3 Au atoms on average. In view of the presented results, a new growth model for the TiO2(110) system involving vacancy-cluster complex diffusion is presented.
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Cites
Electrochemical Photolysis of Water at a Semiconductor Electrode
FUJISHIMA, A., & HONDA, K. (1972) · Nature · doi:10.1038/238037a0 · Cited by 34,169
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Cited by
The Structure of Catalytically Active Gold on Titania
Chen, M. S., & Goodman, D. W. (2004) · Science · doi:10.1126/science.1102420 · Cited by 1,620
Well-Defined Materials for Heterogeneous Catalysis: From Nanoparticles to Isolated Single-Atom Sites
Li, Z., Ji, S., Liu, Y., Cao, X., Tian, S., Chen, Y., Niu, Z., & Li, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00311 · Cited by 1,245
Ceria Maintains Smaller Metal Catalyst Particles by Strong Metal-Support Bonding
Farmer, J. A., & Campbell, C. T. (2010) · Science · doi:10.1126/science.1191778 · Cited by 964
Insights into the reactivity of supported Au nanoparticles: combining theory and experiments
Janssens, T. V. W., Clausen, B. S., Hvolbæk, B., Falsig, H., Christensen, C. H., Bligaard, T., & Nørskov, J. K. (2007) · Topics in Catalysis · doi:10.1007/s11244-007-0335-3 · Cited by 437
Self-citationCO Oxidation on Rutile‐Supported Au Nanoparticles
Remediakis, I. N., Lopez, N., & Nørskov, J. K. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200461699 · Cited by 409
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Metadata
- Authors
- Wahlström, E., Lopez, N., Schaub, R., Thostrup, P., Rønnau, A., Africh, C., Lægsgaard, E., Nørskov, J. K., & Besenbacher, F.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2003-01-14
- Volume
- 90
- Issue
- 2
- Pages
- 026101-026101
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2067854040
- Cited by
- 395
- References
- 2
- FWCI
- 19.82
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Wahlström, E., Lopez, N., Schaub, R., Thostrup, P., Rønnau, A., Africh, C., Lægsgaard, E., Nørskov, J. K., & Besenbacher, F. (2003). Bonding of Gold Nanoclusters to Oxygen Vacancies on RutileTiO2(110). Physical Review Letters. https://doi.org/10.1103/physrevlett.90.026101
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