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Conformal Miniaturization of Domains with Low Domain-Wall Energy: Monoclinic Ferroelectric States near the Morphotropic Phase Boundaries
Abstract
A theory is developed for intermediate monoclinic (FE(m)) phases near morphotropic phase boundaries in ferroelectrics of complex oxides. It is based on the conformal miniaturization of stress-accommodating tetragonal domains under the condition of low domain-wall energy density. The microdomain-averaged lattice parameters are determined and attributed to the parameters of an adaptive monoclinic phase. The theory is applied to the temperature, electric field, and compositional dependent FE(m) lattice parameters. The predictions of the theory are rigidly obeyed over the entire FE(m) stability range.
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Citations
Cited by
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Liu, W., & Ren, X. (2009) · Physical Review Letters · doi:10.1103/physrevlett.103.257602 · Cited by 2,764
BaTiO3-Based Piezoelectrics: Fundamentals, Current Status, and Perspectives
Acosta, M., Novak, N., Rojas, V., Patel, S., Vaish, R., Koruza, J., Rossetti, G. A., & Rödel, J. (2017) · Applied Physics Reviews · doi:10.1063/1.4990046 · Cited by 1,451
Origin of morphotropic phase boundaries in ferroelectrics
Ahart, M., Somayazulu, M., Cohen, R. E., Ganesh, P., Dera, P., Mao, H.-K., Hemley, R. J., Ren, Y., Liermann, P., & Wu, Z. (2008) · Nature · doi:10.1038/nature06459 · Cited by 914
The origin of ultrahigh piezoelectricity in relaxor-ferroelectric solid solution crystals
Li, F., Zhang, S., Yang, T., Xu, Z., Zhang, N., Liu, G., Wang, J., Wang, J., Cheng, Z., Ye, Z.-G., et al. (2016) · Nature Communications · doi:10.1038/ncomms13807 · Cited by 745
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Metadata
- Authors
- Jin, Y. M., Wang, Y. U., Khachaturyan, A. G., Li, J. F., & Viehland, D.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2003-11-06
- Volume
- 91
- Issue
- 19
- Pages
- 197601-197601
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2002957636
- Cited by
- 309
- References
- 0
- FWCI
- 2.75
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Jin, Y. M., Wang, Y. U., Khachaturyan, A. G., Li, J. F., & Viehland, D. (2003). Conformal Miniaturization of Domains with Low Domain-Wall Energy: Monoclinic Ferroelectric States near the Morphotropic Phase Boundaries. Physical Review Letters. https://doi.org/10.1103/physrevlett.91.197601
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
