The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Exciton Delocalization and Superradiance in Tetracene Thin Films and Nanoaggregates
Abstract
The structure and dynamics of luminescent excitons in tetracene thin films and nanoaggregates are investigated using time-resolved spectroscopy and theoretical calculations. The orientation of tetracene's transition dipole moment along its short molecular axis leads to properties qualitatively different from those observed in aggregates of phenylene-vinylene and thiophene oligomers, despite similar crystal structures. The spectral shape, temperature dependence, and radiative lifetime are consistent with a short-lived superradiant exciton delocalized over approximately 10 tetracene molecules.
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Citations
Cites
The exciton model in molecular spectroscopy
Kasha, M., Rawls, H. R., & Ashraf El-Bayoumi, M. (1965) · Pure and Applied Chemistry · doi:10.1351/pac196511030371 · Cited by 4,253
Cited by
The exciton model in molecular spectroscopy
Kasha, M., Rawls, H. R., & Ashraf El-Bayoumi, M. (1965) · Pure and Applied Chemistry · doi:10.1351/pac196511030371 · Cited by 4,253
Hestand, N. J., & Spano, F. C. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00581 · Cited by 1,904
Self-citationMolecular Semiconductors in Organic Photovoltaic Cells
Hains, A. W., Liang, Z., Woodhouse, M. A., & Gregg, B. A. (2010) · Chemical Reviews · doi:10.1021/cr9002984 · Cited by 935
The energy barrier in singlet fission can be overcome through coherent coupling and entropic gain
Chan, W.-L., Ligges, M., & Zhu, X.-Y. (2012) · Nature Chemistry · doi:10.1038/nchem.1436 · Cited by 339
The Structure and Dynamics of Molecular Excitons
Bardeen, C. J. (2014) · Annual Review of Physical Chemistry · doi:10.1146/annurev-physchem-040513-103654 · Cited by 264
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Metadata
- Authors
- Lim, S.-H., Bjorklund, T. G., Spano, F. C., & Bardeen, C. J.
- Venue
- Physical Review Letters
- Publisher
- American Physical Society (APS)
- Published
- 2004-03-12
- Volume
- 92
- Issue
- 10
- Pages
- 107402-107402
- ISSN
- 0031-9007 (ISSN-L)
- 1079-7114
- OpenAlex
- W2052758200
- Cited by
- 279
- References
- 1
- FWCI
- 5.12
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lim, S.-H., Bjorklund, T. G., Spano, F. C., & Bardeen, C. J. (2004). Exciton Delocalization and Superradiance in Tetracene Thin Films and Nanoaggregates. Physical Review Letters. https://doi.org/10.1103/physrevlett.92.107402
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
